煤炭模型化合物.pdf

JOURNAL 01 ANALYTICAL and APPLIED PYROLYSIS Journal of Analytical and Applied Pyroylsis ELSEVIER 34 (1995) 47-63 Thermal decomposition of two coal model compounds - pyridine and 2-picoline. Kinetics and product distributions Emi Ikeda, John C. Mackie * Department oj Physicul and Theoretical Chemistry, University of’ Sydney, Sydney, NSW 2006. Australia Received 25 August 1994; accepted in final form 9 November 1994 Abstract The thermal decomposition of two coal model compounds, pyridine and 2-picoline, has been studied in a completely stirred fused-silica reactor over the temperature range 1060- 1240 K at pressures between 8.0 and 13.3 kPa and at reactor residence times between 1 and 5 s. Profiles of major products and kinetics of thermal decomposition of both compounds are given and a detailed investigation by GC/MS of the minor products of decomposition has been made. Profiles of pyridine and its major products of decomposition can be satisfactorily modelled by a homogenous gas phase kinetic model. The rate of decomposition of 2-picoline was faster than predicted by a homogenous gas phase mechanism and