Pretreatment of microcrystalline cellulose in organic electrolyte solutions for enzymatic hydrolysis 英文参考文献.docVIP

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Pretreatment of microcrystalline cellulose in organic electrolyte solutions for enzymatic hydrolysis 英文参考文献.doc

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Pretreatment of microcrystalline cellulose in organic electrolyte solutions for enzymatic hydrolysis 英文参考文献

Tianetal.BiotechnologyforBiofuels2011,4:53 /content/4/1/53 RESEARCH OpenAccess Pretreatmentofmicrocrystallinecellulosein organicelectrolytesolutionsforenzymatic hydrolysis Xiao-feiTian1,2,ZhenFang1*,DanJiang1,3 andXi-yanSun1,2 Abstract Background:Previousstudieshaveshownthatthecrystallinestructureofcelluloseisnegativelycorrelatedwith enzymaticdigestibility,therefore,pretreatmentisrequiredtobreakdownthehighlyorderedcrystallinestructurein cellulose,andtoincreasetheporosityofitssurface.Inthepresentstudy,anorganicelectrolytesolution(OES) composedofanionicliquid(1-allyl-3-methylimidazoliumchloride([AMIM]Cl))andanorganicsolvent(dimethyl sulfoxide;DMSO)wasprepared,andusedtopretreatmicrocrystallinecelluloseforsubsequentenzymatichydrolysis; toourknowledge,thisisthefirsttimethatthismethodhasbeenused. Results:Microcrystallinecellulose(5wt%)rapidlydispersedandthencompletelydissolvedinanOESwithamolar fractionof[AMIM]ClperOES(c [AMIM]Cl)ofgreaterthanorequalto0.2at110°Cwithin10minutes.Thecellulose wasregeneratedfromtheOESbyprecipitationwithhotwater,andenzymaticallyhydrolyzed.Asthec [AMIM]Cl of theOESincreasedfrom0.1to0.9,boththehydrolysisyieldandinitialhydrolysisrateoftheregeneratedcellulose alsoincreasedgradually.AftertreatmentusingOESwithc [AMIM]Cl of0.7,theglucoseyield(54.1%)was7.2times thatofuntreatedcellulose.Thispromotionofhydrolysisyieldwasmainlyduetothedecreaseinthedegreeof crystallinity(thatis,thecrystallinityindexofcelluloseI). Conclusions:AnOESof[AMIM]ClandDMSOwithc [AMIM]Cl of0.7waschosenforcellulosepretreatmentbecause itdissolvedcelluloserapidlytoachieveahighglucoseyield(54.1%),whichwasonlyslightlylowerthanthevalue (59.6%)obtainedusingpure[AMIM]Cl.OESpretreatmentisacost-effectiveandenvironmentallyfriendlytechnique forhydrolysis,becauseit1)usesthelessexpensiveOESinsteadofpureionicliquids,2)shortensdissolutiontime, 3)requireslowerenergyforstirringandtransporting,and4)isrecyclable. Background withenzymaticdigestibility[3].Therefore,pretrea