Pyrite oxidation inhibition by a cross-linked lipid coating 英文参考文献.docVIP

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Pyrite oxidation inhibition by a cross-linked lipid coating 英文参考文献.doc

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Pyrite oxidation inhibition by a cross-linked lipid coating 英文参考文献

Pyriteoxidationinhibitionbyacross-linkedlipidcoating XiangZhang,aMichaelJ.Borda,bMartinA.A.SchoonenbandDanielR.Strongin*a aDepartmentofChemistry,TempleUniversity,Philadelphia,PA19122. E-mail:daniel.strongin@temple.edu bGeosciencesDepartment,TheStateUniversityofNewYorkatStonyBrook, StonyBrook,NY11794-2100 Article Paper Received26thFebruary2003,Accepted21stMay2003 FirstpublishedasanAdvanceArticleontheweb29thMay2003 Theeffectofadiacetylene-containingphospholipidontheoxidationofpyrite,FeS2,wasinvestigated.Earlier workreportedbyourresearchgroupshowedthattheadsorptionof1,2-bis(10,12-tricosadiynoyl)-sn-glycero-3- phosphocholineonpyritesuppressedtheextentofitsoxidationbyabout75%overaspeci?ctimeperiod. Resultspresentedhereshowthatthepre-exposuretoUVradiationofthislipidaftersorptionontopyrite resultsina90%suppression.Attenuatedtotalre?ection(ATR)Fouriertransforminfra-redspectroscopy (FTIR)suggeststhattheUVirradiationofthelipiddoesnotresultindegradationoftheadsorbedlayer.Itis believedthattheUVexposureresultsinthecross-linkingandpolymerizationoftheadsorbedphospholipidinto arelativelyimpermeablebarrierthatseparatesthepyritefromtheaqueousphase.Theresultsofthisstudy mighthaveimplicationsfortheprotectionofpyritefromoxidationintheenvironment. 1. Introduction In this contribution we extend our investigation of 23:2 DiynePCasanadsorbedphasethatinhibitspyriteoxidation. There is signi?cant interest in reducing the amount of metal sul?deoxidationintheenvironment.Exposureofminewaste containingmetalsul?des,suchaspyrite,toairandwaterleads Priorstudieshaveshownthattheultra-violet(UV)irradiation ofthislipid,8whichhasdiacetylenegroupsinitshydrocarbon tails,leadstocrosslinkingandpolymerizationincircumstances where there is a favorable alignment of neighboring lipid molecule tails. The scienti?c hypothesis in our research is thatthecross-linking(i.e.,polymerization)willleadtofurther pyriteoxidationinhibition,relativetotheunpolymerizedlipid, by providing a signi?cant barrier between the pyrite