Synthesis of Ethylenic and Acetylenic Triorganotins with Bulky Organic Ligands 英文参考文献.docVIP

439 Molecules 2000, 5 Synthesis of Ethylenic and Acetylenic Triorganotins with Bulky Organic Ligands V. Dodero, L.C. Koll and J.C. Podestá Instituto de Investigaciones en Química Orgánica, Departamento de Química e Ing.Qca., Universidad Nacional del Sur, Av. Alem 1253, 8000 Bahía Blanca, Argentina E-mail: jpodesta@criba.edu.ar Abstract: The syntheses of trineophyl- (1a) and tri-(-)-menthylstannyl phenylacetylene (1b) as well as that of (E)-1-trineophylestannyl-2-phenylethene (2) and (E)-1-trineophylstannyl- 1,2-diphenylethene (3) are described. The hydrostannation of 1a with an excess