化学基础第一章1精选.ppt

例题-1 2N2(g)+5O2(g)+6H2(g)==4NO(g)+6H2O(g) (1) 1/2N2(g)+1/2O2(g)==NO(g) ?rHm?= ?fHm?(NO,g) 2N2(g)+2O2(g)==4NO(g) ?rHm?(a)= 4?fHm?(NO,g) 2O2(g)+6H2(g)==6H2O(g) ?rHm?(b)= 6?fHm?(H2O,g) ?rHm?(1) = ?rHm?(a)+?rHm?(b) = [4?fHm?(NO,g)+6?fHm?(H2O,g)] =? (NO,g) 4 (H2O,g) 6 (NH3,g) 4 (O2,g) 5 2N2(g)+5O2(g)+6H2(g)==4NH3(g)+5O2(g) (2) ?rHm?(2)= [4?fHm?(NH3,g)+5?fHm?(O2,g)] 由盖斯定律，(1)-(2): 4NH3(g)+5O2(g) ==4NO(g)+6H2O(g) (3) ?rHm?(3)= ?rHm?(1)-?rHm?(2) = [4?fHm?(NO,g)+6?fHm?(H2O,g)] -[4?fHm?(N