Electrochemical Reduction of Coumarins at a Film-Modified Electrode and Determination of Their Levels in Essential Oils and Traditional Chinese Herbal Medicines.docVIP

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Electrochemical Reduction of Coumarins at a Film-Modified Electrode and Determination of Their Levels in Essential Oils and Traditional Chinese Herbal Medicines.doc

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Electrochemical Reduction of Coumarins at a Film-Modified Electrode and Determination of Their Levels in Essential Oils and Traditional Chinese Herbal Medicines

Molecules 2009, 14, 3538-3550; doi:10.3390/moleculeOPEN ACCESS molecules ISSN 1420-3049 /journal/molecules Article Electrochemical Reduction of Coumarins at a Film-Modified Electrode and Determination of Their Levels in Essential Oils and Traditional Chinese Herbal Medicines Lai-Hao Wang * and Hsiu-Hua Liu Department of Applied Chemistry, Chia Nan University of Pharmacy and Science, 60 Erh-Jen Road, Section 1, Jen Te, Tainan 71743, Taiwan; E-mail: appys31@.tw (H-H. L.) * Author to whom correspondence should be addressed; E-mail: e201466wang@; Fax: +886-6-266-7319. Received: 22 June 2009; in revised form: 26 August 2009 / Accepted: 9 September 2009 / Published: 11 September 2009 Abstract: The electrochemical reduction of coumarins on glassy carbon and electrodeposited metal electrodes was investigated in a Britton-Robinson buffer (pH 1.87-11.98). The effects of various factors, such as the deposition material, time, and concentration of mercury, on the precision of the analysis were explored. The possible reaction mechanism of the reduction process with regards to scan rates, peak potentials, and currents is discussed. Electroreduction was used to quantitatively determine the levels of coumarins in some essential oils and traditional Chinese herbal medicines. A comparison with high performance liquid chromatography analysis results shows good agreement. Keywords: coumarins; essential oils and medicinal products; mercury-film electrode 1. Introduction Coumarins, with a 2H-1-benzopyran-2-one nucleus, and furocoumarins (psoralens, 7H-furo[3,2-g[1]benzopyran-7-one]) are biologically active compounds with effective anti-convulsant, anti-tumoral, anti-inflammatory, and anti-viral properties [1-7]. Additionally, coumarins have been Molecules 2009, 14 3539 widely used as flavoring compounds because of their sweet and aromatic odor [8]. Coumarin dyes are orga