Electrochemical Synthesis and Structural Characterization of a Novel Mixed-valence Copper (I)-copper (II) Complex {[Bis(ethylenediamine) Copper (II)] Bis[diiodocuprate (I)]}.docVIP

下载本文档

11
0
约 10页
2017-05-16 发布于上海
举报
版权申诉

Electrochemical Synthesis and Structural Characterization of a Novel Mixed-valence Copper (I)-copper (II) Complex {[Bis(ethylenediamine) Copper (II)] Bis[diiodocuprate (I)]}.doc

1、本文档共10页，可阅读全部内容。
2、原创力文档（book118）网站文档一经付费（服务费），不意味着购买了该文档的版权，仅供个人/单位学习、研究之用，不得用于商业用途，未经授权，严禁复制、发行、汇编、翻译或者网络传播等，侵权必究。
3、本站所有内容均由合作方或网友上传，本站不对文档的完整性、权威性及其观点立场正确性做任何保证或承诺！文档内容仅供研究参考，付费前请自行鉴别。如您付费，意味着您自己接受本站规则且自行承担风险，本站不退款、不进行额外附加服务；查看《如何避免下载的几个坑》。如果您已付费下载过本站文档，您可以点击这里二次下载。
4、如文档侵犯商业秘密、侵犯著作权、侵犯人身权等，请点击“版权申诉”（推荐），也可以打举报电话：400-050-0827(电话支持时间：9:00-18:30)。
5、该文档为VIP文档，如果想要下载，成为VIP会员后，下载免费。
6、成为VIP后，下载本文档将扣除1次下载权益。下载后，不支持退款、换文档。如有疑问请联系我们。
7、成为VIP后，您将拥有八大权益，权益包括：VIP文档下载权益、阅读免打扰、文档格式转换、高级专利检索、专属身份标志、高级客服、多端互通、版权登记。
8、VIP文档为合作方或网友上传，每下载1次，网站将根据用户上传文档的质量评分、类型等，对文档贡献者给予高额补贴、流量扶持。如果你也想贡献VIP文档。上传文档

Electrochemical Synthesis and Structural Characterization of a Novel Mixed-valence Copper (I)-copper (II) Complex {[Bis(ethylenediamine) Copper (II)] Bis[diiodocuprate (I)]}

Molecules 2007, 12, 1410-1419 molecules ISSN 1420-3049 ? 2007 by MDPI /molecules Full Paper Electrochemical Synthesis and Structural Characterization of a Novel Mixed-valence Copper (I)-copper (II) Complex: {[Bis(ethylenediamine) Copper (II)] Bis[diiodocuprate (I)]} Lida Fotouhi 1,*, Saeed Dehghanpour 1, Majid M. Heravi 1 and Mahboobeh Dashti Ardakani 2 1 Department of Chemistry, School of Science, Azzahra University, P.O.Box 1993891176, Tehran, Iran 2 Institute and Outpatient Clinic for Occupation and Social Medicine of the Justus-Liebig-University of Giessen, Aulweg 129 III, 35392 Giessen, Federal Republic of Germany; Email: dashti_290@ * Author to whom correspondence should be addressed; E-mails: lida_fotouhi@ or lfotouhi@azzhra.ac.ir Received: 6 June 2007; in revised form: 9 July 2007 / Accepted: 10 July 2007 / Published: 12 July 2007 Abstract: A novel, mixed-valent copper(I)-copper(II) complex, {[bis(ethylene- diamine)copper(II)] bis[diiodocuprate(I)]} (1), has been prepared by electrochemical dissolution of a sacrificial copper anode in a solution of ethylenediamine (en), I2 and tetraethylammoniumperchlorate (TEAP) as supporting electrolyte in acetonitrile (AcN) and characterized by single-crystal X-ray structure determination. The crystal structure of the complex 1 shows that it consists of a CuI2 polymer formed from I- ligands bridging Cu(I) ions, with a nearly square planar geometry of bivalente Cu(II) atoms chelated by two ethylenediamine ligands. The results also show that direct electrosynthesis of the complex had high current efficiency, purity and electrolysis yield. Keywords: Copper (I/II); complex; electrosynthesis; ethylenediamine; diiodocuprate(I). Molecules 2007, 12 1411 Introduction The design of complex molecular architectures based on transition metal atoms and organic ligands is an important goal for synthetic chemistry as it provides the opportunity to control o