Enhanced Photophysical Properties of Nanopatterned Titania NanodotsNanowires upon Hybridization with Silica via Block Copolymer Templated Sol-Gel Process.docVIP

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Enhanced Photophysical Properties of Nanopatterned Titania NanodotsNanowires upon Hybridization with Silica via Block Copolymer Templated Sol-Gel Process.doc

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Enhanced Photophysical Properties of Nanopatterned Titania NanodotsNanowires upon Hybridization with Silica via Block Copolymer Templated Sol-Gel Process

Polymers 2010, 2, 490-504; doi:10.3390/polym2040490 OPEN ACCESS polymers ISSN 2073-4360 /journal/polymers Article Enhanced Photophysical Properties of Nanopatterned Titania Nanodots/Nanowires upon Hybridization with Silica via Block Copolymer Templated Sol-Gel Process Dinakaran Kannaiyan 1,?, Saji Thomas Kochuveedu 1,?, Yoon Hee Jang 1, Yu Jin Jang 1, Ji Yong Lee 1, Jieun Lee 1, Juyon Lee 1, Jooyong Kim 2 and Dong Ha Kim 1,* 1 Department of Chemistry and Nano Science, Division of Molecular and Life Sciences, College of Natural Sciences, Ewha Womans University, 11-1 Daehyun-dong, Seodaemun-gu, Seoul 120-750, Korea; E-Mails: dinakark@ (D.K.); stkochuveedu@ (S.T.K.); 1985hee@ (Y.H.J.); breezeyam@ (Y.J.J.); shinjo7@ (J.Y.L.); jieun0122@ (J.L.); ashez@ (J.L.) 2 Department of Organic Materials and Fiber Engineering, Soongsil University, 511 Sangdo-Dong, Dongjak-Gu, Seoul 156-743, Korea; E-Mail: jykim@ssu.ac.kr (J.K.) * Author to whom correspondence should be addressed; E-Mail: dhkim@ewha.ac.kr; Tel.: +82-2-3277-4124; Fax: +82-2-3277-3419. ? The authors contributed equally to this work. Received: 28 September 2010; in revised form: 18 October 2010 / Accepted: 21 October 2010 / Published: 25 October 2010 Abstract: We fabricated titanium dioxide (TiO2)-silica (SiO2) nanocomposite structures with controlled morphology by a simple synthetic approach using cooperative sol-gel chemistry and block copolymer (BCP) self-assembly. Mixed TiO2-SiO2 sol-gel precursors were blended with amphiphilic poly(styrene-block-ethylene oxide) (PS-b-PEO) BCPs where the precursors were selectively incorporated into the hydrophilic PEO domains. Changing the volumetric ratio of TiO2-SiO2 sol-gel precursor from 5% to 20%, a stepwise structural inversion occurred from nanodot arrays to discrete nanowires. Template free hybrid inorganic nanostructures were produced after the removal of PS-b-PEO by irradiation of UV light. The mor