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Ensiling of crops for biogas production effects on methane yield and total solids determination.doc

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Ensiling of crops for biogas production effects on methane yield and total solids determination

Kreugeretal.BiotechnologyforBiofuels2011,4:44 /content/4/1/44 RESEARCH OpenAccess Ensilingofcropsforbiogasproduction:effectson methaneyieldandtotalsolidsdetermination EmmaKreuger*,IvoAchuNgesandLovisaBj?rnsson Abstract Background:Ensilingisacommonmethodofpreservingenergycropsforanaerobicdigestion,andmany scientificstudiesreportthatensilingincreasesthemethaneyield.Inthisstudy,theensilingprocessandthe methaneyieldsbeforeandafterensilingwerestudiedforfourcropmaterials. Results:Thechangesinwetweightandtotalsolids(TS)duringensilingweresmallandthelossofenergy negligible.Themethaneyieldsrelatedtowetweightandtovolatilesolids(VS)werenotsignificantlydifferent beforeandafterensilingwhentheVSwerecorrectedforlossofvolatilecompoundsduringTSandVS determination.However,whentheTSweremeasuredaccordingtostandardmethodsandnotcorrectedforlosses ofvolatilecompounds,theTSlossduringensilingwasoverestimatedformaizeandsugarbeet.Thesame methodologicalerrorleadstooverestimationofmethaneyields;whenTSandVSwerenotcorrectedthemethane yieldappearedtobe51%higherforensiledthanfreshsugarbeet. Conclusions:Ensilingdidnotincreasethemethaneyieldofthestudiedcrops.Publishedmethaneyields,aswell asotherinformationonsilagerelatedtouncorrectedamountsofTSandVS,shouldberegardedwithcaution. Keywords:biogas,anaerobicdigestion,methanepotential,biofuel,ethanol,volatilefattyacids,drymatter,total solids,volatilesolids,ensiling,silage Background At the beginning of the 20th century it was reported Biogasproductionusingenergycropsasthemainfeed- that oven drying gives inaccurate values of the DM stockisattractingincreasingattention.Germanyislead- whenthesamplecontainsvolatilecompounds.Itshould ing the field, with almost 3, 900 biogas plants in therefore notbeapplied tosilage asitcontains varying operation in2009, themajority usingensiled crops [1]. amounts of volatile fatty acids (VFAs), lactic acid, Ensiling is a traditional method of preserving animal ammoniaand alcohols formedduring theensiling pro-