高分子毕业论文学习.docVIP

1 针对此优秀学士学位论文,请大家用样式标出各级标题,并自动生成目录.首页页眉为湖北工业大学学士学位论文，其余页眉为各自姓名。用word自带格式在文中应有地方标注参考文献 2 用office自带模板画一个减压蒸馏装置 3 chemicaloffice 课间ppt，51，52，60，69 4.P110,P113,P177画出结构图,并对给出110面图进行分析，以及其氢谱和碳谱 5把110面图转化为3D,并对其进行最低能量的排布，计算能量 毕 业 设 计（论 文） 题 目 单分散光、温度双响应中空微球的制备及其性质 姓 名 学 号 所在学院 专业班级 指导教师 日 期 摘 要 近年来，功能化聚合物微球的制备技术越来越成熟，其在很多领域有十分广泛应用：电子信息、生物医药、新材料等。光源凭借其获取快捷及可远程操控的优势，使得光敏性微球的研究成为了研究的热点。目前光敏性微球主要由含光敏基元的嵌段共聚物自组装及层层自组装制备得到，但是其缺陷在于它们的结构并不稳固。 本文以蒸馏沉淀聚合法合成了单分散的双响应中空微球。以3-（甲基丙烯酰氧）丙基三甲氧基硅烷（MPS）表面改性的球为模板温度响应的N-异丙基丙烯酰胺(NIPAM)为单体光响应的对二甲基丙烯酰胺偶氮苯(BMAAB)为交联剂加少量二乙烯基苯(DVB)助交联剂，并以偶氮二异丁腈(AIBN)为引发剂，合成PNIPAM核壳微纳米粒子。再氢氟酸除去核形成具有结构的光温敏微球。具有最低临界温度 (LCST)。TEM、FT-IR等手段对的组成和结构进行了表征。结果表明采用蒸馏沉淀聚合法成功制备单分散聚N-异丙基丙烯酰胺中空微球，该微球具有光温度。The fabrication methods of polymer microspheres are increasingly mature, and been applied in electric information, new materials and biologic medication areas, etc. Light has attracted more and more attention since it can be localized in time and space and be triggered from outside of the system, so it is of great importance in developing photo-responsive microspheres. At present, photo-responsive microspheres have been normally fabricated through amphiphilic copolymer containing photoresponsive moieties by self-assemble methods and their structures were not robust. In this thesis, we synthesized thermal and photo dual stimuli-responsive monodisperse hollow polymeric microspheres via a novel distillation precipitation polymerization method. The core-shell particles were synthetized with SiO2 particles as a template which was modified by [3-(Methacryloyloxy)propyl]trimethoxysilane (MPS), thermo-responsive NIPAM as monomer, photoresponsive BMAAB as cross-linker, a few amount of DVB as aid cross-linker, and AIBN as initiator. Then using HF acid to selectively etch SiO2 core, we prepared the thermal and photo dual stimuli-responsive PNIPAM polymeric microspheres wi