红磷酚醛和三聚氰胺阻燃的协同作用.pdfVIP

Polymer Degradation and Stability 91 (2006) 1996e2002 /locate/polydegstab Synergistic effect of red phosphorus, novolac and melamine ternary combination on flame retardancy of poly(oxymethylene) Hatsuhiko Harashina a,b, Yoshihisa Tajima b, Takahito Itoh a,* a Department of Chemistry for Materials, Faculty of Engineering, Mie University, 1577 Kurima Machiya-cho, Tsu-shi, Mie 514-8507, Japan b Polyplastics Co., Ltd., 973 Miyajima, Fuji-shi, Shizuoka 416-8533, Japan Received 28 October 2005; received in revised form 14 February 2006; accepted 21 February 2006 Available online 2 May 2006 Abstract New flame retardant system for poly(oxymethylene) (POM) has been studied. The combination of red phosphorus with novolac and mela- mine was found to act as an effective flame retardant of POM. The base POM exhibited very low limiting oxygen index (LOI) value of 15.3, while the flame retarded POM gave remarkably high LOI value of 37.5 and UL94 V-1 ranking without dripping at 0.8 mm thickness. The results of cone calorimetry, thermogravimetry and FTIR analysis suggested that the flame retarding mechanism is the intumescent char formation in the condensed phase. Novolac having a phenolic hydroxyl group is miscible with POM, and in the flaming process, red phosphorus yields phosphine and its acidic product such as phosphoric acid due to hydrolysis and oxidation reactions. In addition, all of novolac, melamine and phosphine are able to readily react with formaldehyde generated from POM during burning to give the reinforced and cross-linked char network through the polyaddition and polycondensation reactions