温度对AZ91D镁合金初期大气腐蚀行为的影响.pdfVIP

2(阴年2 月 February ， 2αn 失效分析与预防 Vo1. 4 ,No.l 第4 卷第1 期 温度对 AZ91D 镶合金初期大气腐蚀行为的影晌 梁健能，林翠 (南昌航空大学，材料科学与工程学院，南昌 33创63 ) [摘 要]采用金相显微镜、扫描电镜 (SEM) ，能谱仪 (ED町、 X-射线衍射 (XRD) 研究温度对AZ9ID 筷合金初期大 气腐蚀的影响，并且分析了 AZ91D 续合金在不同温度的大气环境中的腐蚀形貌和腐蚀产物。试验结果表明:续含金在20 t大气环绕中的腐蚀增重随时间变化较小.30 C大气环境中的腐蚀增重在 196 h 后加速，腐蚀428 h 后续合金在30 c大 气中的腐蚀增重约为20 c的 2 倍。 20 c和 30 c大气环境中的腐蚀产物主要以胞状形态生长，胞状产物表面附着大量的 针状产物。随温度升高，初期腐蚀速率提高，腐蚀产物覆盖率增加。 [关键词]温度; AZ91D 续合金E 初期大气腐蚀 [中图分类号] TGI74 [文献标识码] A [文章编号] 1673-ti214(2009)01α川崎 Influence of Temperature on Initial Atmospheric Corrosion Behavior of AZ91 D Magnesium Alloy 口ANG Jian-ne吨， UN Cui (hool (扩 Material ience Techrwlo.盯， Nancha昭Ha.略加ng University, Nanchang 33创则， China) Abstr四t :The influence of temperat田e on initial atmo叩heric corrosion behavior of AZ91 D magnesium alloy Wiωstudied by opti- cal microscopy (OM) , sc皿ni吨electron microscopy (SEM) , ene唱y dispersion spectrum (EDS) and X-ray diffraction (XRD). The chemical composition and appearance of the corr回ion products at different temperatures in atmosphere were analyzed. The results show that the mass gain of AZ91 D magnesium alloy in atmosphere increased exponentially at the initial stage. 白le mass gain of AZ91 D at 30 C was nearly double that at 20 C after testing for 428 h. The m剧伊in of AZ91 D increased slowly during the whole proc回s of testing at 20 C. However , the mωs gain of AZ9 lD began ωaccelerate after testing for 196 h at 30 C. The corrosion products at 20 C or 30 C mainly presented cellular appearance , and there were many needle-like corrosion products adhering to the surface of the