亚微结构叶状铜的水热制备条件研究.pdfVIP

学兔兔 第26卷第5期 粉末冶金技术 Vo1．26，No．5 2008年 10月 Powder Metallurgy Technology Oct．2008 亚微结构叶状铜的水热制备条件研究* 陈庆春 )， ) 刘晓东 )，2’ 邓慧宇 )，2) 1)(东华理工大学材料科学与工程系，江西抚州 344000) 2)(东华理工大学核资源与环境教育部重点实验室，南昌330013) 摘 要： 用CuSO4·5H2O和NaOH为主要原料，考察了作为还原剂的多元醇种类、多元醇的量、水热反应温 度、NaOH的量等条件对产物铜的形貌的影响。借助x射线衍射(XRD)和扫描电镜(SEM)表征，结果表明， 在所研究范围内，得到具有亚微结构的叶状铜的水热制备条件是：D一山梨醇作还原剂，醇与Cu 的摩尔比 不超过 1／2，水热温度180(2；NaOH的量不影响叶状铜的形成。 关键词：亚微结构；叶状铜；水热制备；晶体生长；条件 Study on the hydrothermal preparation conditions flaky copper powder with submicrostructure Chen Qingchun ’ ，Liu Xiaodong ’ ．Deng Huiyu I)(Department of Materials Science and Engineering，East China Institute of Technology， Fuzhou Jiangxi 344000，China) 2)(Key Laboratory of Nuclear Resources and Environment，East China Institute of Technology Ministry of Education，Nanchang 330013，China) Abstract：Effects of type and amount of reducer polyol，hydrothermal reaction temperature and amount of NaOH on the morphology of copper powder fabricated from CuSO4·5H2O and NaOH were studied by XRD and SEM．Results show that the hydrothermal conditions to obtain flaky copper powder with submicrostructure under the study conditions are：D-sorbitol as reducer，molar ratio of polyol to Cu not more than 1／2 and hydrothermal temperature of 180(3．The am ount of NaOH has no effect on the morphology． Key words：submicrostructure；flaky copper powder；hydrothermal synthesis；crystal growth；conditions 超细铜粉可用作高效催化剂、导电涂料，还可用 等在水热条件下合成了六方柱状的Cu2O晶须_1 。 作导电复