低温燃烧法合成纳米MgO粉体工艺的研究.pdfVIP

学兔兔 第19卷第2期 粉 末 冶 金 工 业 Vo1．19 No．2 2009年 4月 POWDER METALLURGY INDUSTRY Apr．2009 低温燃烧法合成纳米MgO粉体工艺的研究 陈 爽，严红革，陈 超，李红艳 (湖南大学材料科学与工程学院，长沙 41OO82) 摘 要：以硝酸镁、柠檬酸及氨水为原料，用低温燃烧法成功制备了纳米MgO粉体。以推进 剂化学为理论依据，得出了硝酸镁与柠檬酸的最佳摩尔配比。考察了前驱体溶液的pH值、加 水量、点火温度等工艺参数对反应过程及最终产物的影响。用X—ray衍射(XRD)及透射电镜 (TEM)等分析方法对合成的粉体进行了表征。在优选的工艺条件下，获得了晶粒尺寸为9～ 25 am的纳米 MgO粉体。 关键词：低温燃烧法；纳米MgO粉体；工艺参数 ‘ 中图分类号：TF123．7 文献标识码：A 文章编号：1006—6543(2009)02—0036—05 SYNTHESIS OF MgO NANOCRYSTALLINE POWDER BY LOW—TEMPERATURE COMBUST10N CHEN Shuang，YAN Hon~ge，CHEN Chao LI Hong-yan (College of Material Science and Engineering，Hunan University。Changsha 410082-China) Abstract：MgO nanocrystalline powder was prepared by using Mg(NO3)2，citric acid and am— monia via low temperature combustion synthesis．According to thermochemica1 calculation of propellant chemistry，the optimum molar ration of nitrate tO citric acid was obtained．The in— fluences of the precursor solution pH value，the water volume and the heating temperature on the reaction process and the properties of the final product were extensively investiga— ted．Sample characterization was performed by means of X—ray diffraction(XRD)and trans— mission microscopy(TEM)．The processing parameters were optimized and uniform MgO nanocrystalline powder crystals with grain diameter of 9～2 5 nm were obtained． Key words：low temperature combustion；MgO nanocrystaUine powder；processing parameter