双电极电化学沉积法制备FePt纳米颗粒粉末.pdfVIP

学兔兔 第29卷第 1期 粉末冶金技术 Vo1．29．No．1 201 1年 2月 Powder Metallurgy Technology Feb．2011 双电极电化学沉积法制备FePt 纳米颗粒粉末 杜雪岩一 杜春岭 李翠霞 郭海霞 耿丽萍 (兰州理工大学甘肃省有色金属新材料省部共建国家重点实验室，兰州 730050) 摘 要： 采用电化学沉积法制备FePt颗粒。将氯铂酸、硫酸亚铁按一定比例混合成溶液lOOmL，调pH值为 2．5，调节脉冲电源参数制备FePt颗粒，并通过 XRD、TEM、VSM等研究颗粒的微观结构以及宏观磁性能。 XRD分析表明，所制备的FePt纳米颗粒具有面心立方(fcc)结构，在800％热处理后转变为面心四方(fct)结 构；TEM观察显示，颗粒呈类球形，粒径在4nm左右。VSM测试表明，制备的FePt纳米颗粒的矫顽力为零，呈 现超顺磁性。热处理后其矫顽力约为1．2×10 A／m，饱和磁化强度为72．20A-m ／kg。 关键词：电化学；制备；FePt颗粒；磁性 FePt nanoparticles prepared by a double-pole electrodeposited method Du Xueyan，Du Chunling，Li Cuixia，Guo Haixia，Geng Liping (State Key Laboratory of Gansu Advanced Non—ferrous Metal Materials，Lanzhou University of Technology，Lanzhou 730050，China) Abstract：FePt nanoparticles were prepared by an e1ectr0deposited method，in which 100mL of H 2PtC16 and FeSO4 solution with pH value of 2．5 and the pulse power parameters were used．The microstrueture and magnetic properties of nanopartieles were investigated hy XRD，TEM and VSM．XRD results show that FePt nanopartieles are of fcc structure and solne of them transform into fet structure after annealing at 800~C．It can be seen from TEM photos that most of the nanoparticles have a size of around 4．0nm．VSM investigations indicate that the coercivity of the as— synthesized FePt nanopartieles are near zero，implying perties，and about 1．2×1 0 A／m after heat treatment，respectiv