自蔓延反应制备ZrC粉末的形成机制研究.pdfVIP

学兔兔 第29卷第3期 粉末冶金技术 Vol_29．No．3 2011年6月 Powder Metallurgy Technology Jun．2011 自蔓延反应制备ZrC粉末的形成机制研究术 宋谋胜一 冉茂武 (铜仁学院物理与电子科学系，贵州铜仁 554300) 摘 要：利用自蔓延高温合成技术，在A1一zr-c粉末中原位制备了ZrC粉末。通过DTA试验并结合燃烧反 应淬熄处理，研究了Al—zr-c体系原位合成ZrC粉末的反应行为与形成机制。结果表明，在Al—Zr—C粉末中，A1 与Zr之间形成ZrA1 金属间化合物的反应更易发生，然后利用该反应放出的大量热量，c与ZrA1 熔体发生反 应而生成热力学上更稳定的ZrC相，并还原出 一A1相。混合粉末中的Al不仅作为稀释剂来降低反应温度而 抑制ZrC晶粒的长大，更是作为反应物参与了整个合成反应进程。 关键词：ZrC；自蔓延合成；DTA；形成机制 Investigation of formation mechanism of ZrC powder fabricated by self-propagating reaction Song Mousheng，Ran Maowu (Department of Physics and Electronics Science，Tongren University，Tongren Guizhou 554300，China) Abstract：Utilizing self—propagating high—temperature synthesis reaction，ZrC powder was in—situ fabricated in the A1一 Zr-C powders system． Through the DTA experiment together with the quenching treatment during combustion reaction，the reaction behavior and formation mechanism of the in—situ synthesized ZrC was investigated．The results show that in A1一Zr-C mixtures，the reaction of Zr and A1 tO form ZrA13 intermetallic compound more easily occur，and then C reacts with the ZrA13 melt to form more thermodynamically stable ZrC phase utilizing the heat released by the A1-Zr reaction and to reduce to d—A1 phase．A1 in AI—Zr—C compacts acts not only as a diluent decreasing the reaction temperature to inhibit the ZrC grain coarsening，but also as an intermediate reactant participating in the who