草酸盐共沉淀法制备Cu-Sn预合金粉末.pdfVIP

学兔兔 第15卷第5期 粉末冶金材料科学与工程 2010年10月 、，01．15No 5 Materials Science and Engineering of Powder Metallurgy oct．2O1O ． ． ． ． ． ． — — 草酸盐共沉淀法制备Cu．Sn预合金粉末 黄 蓉，陈仕奇 (中南大学 粉末冶金国家重点实验室，长沙 4100831 摘 要：以CuC122H2O，SnC122H2O为原料，草酸为沉淀剂，采用共沉淀一热分解法制备Cu—Sn预合金粉末。采 用x射线衍射仪(xRD)和扫描电子显微镜(SEM)分别分析前驱体粉末及热分解产物的物相组成和微观形貌，并研 究所制备 Cu—Sn预合金粉末的粒度和形貌特征。结果表明：共沉淀前驱体为 CuC2042H2O和 SnC2042H2O的固 溶体，采用共沉淀一热分解法制备出的cu．Sn预合金粉末具有粒度细小、粒度分布窄的特点，其中位径为1．68 gm， 且该合金粉末对前驱体粉末形貌具有继承性。 关键词：Cu—Sn预合金粉末；共沉淀法；热分解；粒度 中图分类号：TF123．12 文献标识码：A 文章编号：1673—0224(2010)5—525—05 Preparation of Cu—Sn prealloyed powder by oxalate c0-precipitati0n method HUANG Rong，CHEN Shi·qi (State Key Labrotary ofPowder Metallurgy，Central South University，Changsha 410083) Abstract：Using CuC12’2H20 and SnC12‘2H20 as raw materials and H2C204‘2H20 solution as precipitator，Cu—Sn prealloyed powder was fabricated by CO—precipitation and thermal decomposition method．The composition and morphology of the prealloyed powder were characterized by X—ray diffraction(XRD)and scanning electronic microscope (SEM)，the chemical composition and the distribution of the particle size was also analyzed．The results show that，the precursor was solid solution of CuC204 2H2 and 8nC204‘2H2O．The particle size of Cu—Sn prealloyed powder prepared by CO—precipitation and thermal decomposition method i