第16沼肼无机化学.ppt

PCl3的水解反应 PCl3+3H2O = H3PO3+3 HCl * Evaluation only. Created with Aspose.Slides for .NET 3.5 Client Profile 5.2.0.0. Copyright 2004-2011 Aspose Pty Ltd. * PCl5的性质： 水解性 极易于水解，随水量多少，产物不同 不完全水解: 当水量不足，生成三氯氧磷和氯化氢： PCl5+ H2O ＝ POCl3+2HCl 过量水中完全水解生成磷酸： POCl3 + 3H2O ＝ H3PO4+3HCl Evaluation only. Created with Aspose.Slides for .NET 3.5 Client Profile 5.2.0.0. Copyright 2004-2011 Aspose Pty Ltd. PCl5: 反应活性高，可与很多物质反应 Evaluation only. Created with Aspose.Slides for .NET 3.5 Client Profile 5.2.0.0. Copyright 2004-2011 Aspose Pty Ltd. * 3、磷的硫化物(不要求) 磷有四种较重要的硫化物：P4S3、P