低标号混凝土用聚羧酸减水剂的制备与应用.pdfVIP

学兔兔 全国中文核心期刊 新癯 蟓 中国科技核心期刊 低标号混凝土用聚羧酸减水剂的制备与应用 付强善，王小兵，熊磊，蒋长清 (常州建筑科学研究院江苏尼高科技有限公司，江苏 常州 213015) 摘要：采用不同分子质量的聚乙二醇单甲醚、甲基丙烯酸、马来酸二甲酯、巯基丙酸、过硫酸铵合成用于低标号混凝土的聚羧 酸减水剂。试验结果表明：醇酸质量比相同的情况下，采用低分子质量MPEG合成的减水剂保坍性好，但掺减水剂混凝土的抗压强 度比采用高分子质量MPEG的要小；马来酸二甲酯、巯基丙酸、过硫酸铵用量分别为3％、0．70％…1 4％时，合成的减水剂综合性能良 好。将合成的聚羧酸减水剂与脂肪族减水剂在低标号混凝土中的应用性能进行了对比并做了成本分析，结果表明，研发的聚羧酸减 水剂性能良好，且在降低混凝土成本上有优势。 关键词：聚羧酸减水剂；脂肪族减水剂；合成：低标号混凝土；应用 中图分类号：TU528．042 文献标识码：B 文章编号：1001—702X(2012)09—0032—03 Preparation and application of polycarboxylic acid superplasticizer used into low grade concrete FU Qiangshan，WANG Xiaobing，XIONG Lei，JIANG Changqing (Changzhou Institute of Building Science，Jiangsu Nigao Science and Technology Co．Ltd．,Changzhou 213015，Jiangsu，China) Abstract：Polycarboxylic acid superplasticizer used into low grade concrete was synthesized with methoxypolyethylene glycol of differentmolecular weights，methacrylic acid，dimethylmMe~e，mercaptopropanoic acid，and ammonium persutfate．The results showed that at the same alkyd quality ration，the low molecular we J ght methoxypolyethylene glycol slump smaller by the time loss， but the compressive strength was smaller than the high molecular methoxypolyethylene glyco1．When the dose of dimethyl maleme， mercaptopropanoic acid，and ammonium persulfate was 3％，O．7％，1．4％，comprehensive performance of concrete was good．Compared with aliphatic superplasticizer，the polycarboxylic acid superplasticizer showed good performance，and had an advantage in lowering cost of low grade concrete． Key words：polycarboxylic acid superplastieizer；aliphatic superplasticizer；synthesis；low grade concrete；application