改性脂肪族减水剂对混凝土抗裂性能的影响.pdfVIP

学兔兔 杆鲤 蟓 中国科技核心期刊 改牲腊肪族减水剂对混凝士 抗裂牲能的影晌 尤迁，周文，蒋亚清，胡飞龙 (河海大学 力学与材料学院，江苏 南京 210098) 摘要：通过引入对氨基苯磺酸和木质素磺酸钠，合成具有磺酸基 (-一sO，H)、氨基 (_NH2)和羟基 (__0H)的改性脂肪族减水剂 (MSAF)，并在此基础上研究了MSAF对混凝土塑性收缩与抗裂性能的影响，通过XRD分析，探讨了MSAF对水泥铝酸盐水化产物 的作用。结果表明：与普通脂肪族减水剂相比，MSAF具有更好的保水作用和空间位阻效应，使混凝土早期塑性收缩降低，开裂面积 减小。MSAF能够抑制GA的水化进程，降低早期的水化反应温度，减少混凝土早期裂缝的产生。 关键词：混凝土；脂肪族减水剂；改性；收缩；抗裂 中图分类号：TU528．042．2 文献标识码：A 文章编号：1001—702X(2015)05—0037—03 Crack resistanceofconcretemixed withmodified sulfonated aliphficseriessuperplasticizer ． YOUQ ，ZHOUWen，JIANGYaqing，HUFeilong (CollegeofMechanicsandMaterials，HohaiUniversity，Nanjing210098，Jiangsu，China) Abstract：By introducing sulfanilic acid and sodium lignosulphonate，the modified sulfonated acetone formaldehyde(MSAF) highefficientwaterreducerwassynthesizedwithsulfonicgroup(一s03H)，aminogroup(一NH2)andhydroxy1．Theplasticshrinkage nad crackresistnaceofconcretemixed witllMSAF was investigated，and effectofMSAF Oilassemblageofaluminatehydrates in cementpasteWas investigatedbyXRD．Experimental resultsindicated thattheplasticshrinkageand thecrackingarea ofconcrete mixed with modified sulfonatedaliphticseriessuperplasticizerdecreased；compraed with aliphtic superplasticizer．MSAF has better waterdispersion effectna d space steric effectwhich isbenefitforcrack resistnaceofconcrete．MSAF can inhibitthe hydration progressofGA，reduceeralyhydrationreactiontemperature，nadreducetheeralycrackofconcrete． Key words：concrete，aliphticsuperplasticizer，modified，shrinkage，crackresistnace