α-半水石膏的制备与应用研究进展.pdfVIP

学兔兔 中国科技核心期刊 新 建巍柑 一 半水石膏的制备与应用研究进展 胡宏“ ，何兵兵 ，薛绍秀 【1．西安建筑科技大学 粉体工程研究所，陕西 西安 710055 2．瓮福(集团)有限责任公司，贵州 福泉 550501] 摘要：根据国内外的研究现状，系统介绍了a一半水石膏的结晶特性、制备方法及应用领域。以二水石膏制备a一半水石膏的过 程为溶解再结晶的过程，制备方法主要包括蒸压水蒸气法和水热法，分析了上述2种制各方法的优势与不足，水热法中的盐溶液法 由于可以加入转晶剂使a一半水石膏向高强度的短柱状晶型转化，该法将随着工艺参数控制方法的完善而得到更为广泛的应用。磷 石膏制备a一半水石膏可以大量消耗磷石膏原料，经济上可行，较理想的制备方法为在磷酸和硫酸介质中实现脱水转化。 关键词：a一半水石膏；机理；制备方法；磷石膏 中图分类号：TQI77．3 文献标识码：A 文章编号：1001—702X(2015)04—0044—05 Research progress on preparation and appfication of仅一calcium sulfate hemihydrate HU Hong1 ，HE Bingbinf，XUE Shaoxiu (1．Institute of Powder and Engineering，Xian University of Architecture and Technology，Xiall 710055，Shaanxi，China． 2．Wengfu Group Co．Ltd，Fuquan 550501，Guizhou，China) Abstract：Crystallization characteristics。preparation and application of d—calcium sulfate hemihydrate were introduced system— atically according to research progress at home and abroad．Process on preparation of a—calcium sulfate hemihydrate by gypsum was a process of dissolution and crystallization．In addition，the preparation methods mainly included autoclave steam method and hydrothermal method．Meanwhile，advantage and shortage of methods above were analyzed．Salt solution method will obtain broader application with the perfectness of parameter control process，due to the fact that the crystal modifier could be added to salt solu— tion in order to make the a—calcium sulfate hemihydrate convert to high intensity short column type crysta1．Finally，the ideal technique of n-calcium sulfate hemihydrate