酸固化剂对酚醛树脂／玻化微珠复合材料性能的影响.pdfVIP

学兔兔 全国中文核心期刊 钎癯建隳 中国科技核心期刊 酸固化剂对酚醛榭脂／玻化微珠 复合材料性链的影响 井强山，杨润桦，申冠飞，刘鹏 (信阳师范学院 非金属材料研究所，河南 信阳 464000) 摘要：以酚醛树脂和玻化微珠为主要原料，在特定条件下酸催化固化成型，制备酚醛树脂／玻化微珠轻质复合材料。通过单因素 法研究了单酸与混酸固化剂对酚醛树脂，玻化微珠复合材料性能的影响。结果表明，使用盐酸和磷酸质量比为2：1，且占酚醛树脂质 量12％的混酸作固化剂时，复合材料性能最优，其抗压强度为1．287 MPa，密度为328 kg／m 。 关键词：酚醛树脂；玻化微珠；轻质复合材料；酸固化剂；性能 中图分类号：TU55 文献标识码：A ． 文章编号：1001—702X(2015)09—0054—03 Influence of acid curing agent on the properties of phenolic resin／vitrified microphere JING Qiangshan，YANG Runhua，SHEN Guanfei，LIU Peng (Institute of Non-metallic Materials，Xinyang Normal University，Xinyang 464000，Henan，China) Abstract：A phenolic／vitrified mierosphere lightweight composite was catalytic thermoformed under certain condition，using acid as curing agent．Effects of strength and density of the lightweight composite materials on single and compounded acid curing agent were investigated by univariate analysis method．Influence of the various types and dosage of acid curing agent on properties were al— SO studied．Experiments results showed that the optimized mass ratio of mix acid(the mass ratio of hydrochloric acid to ortho-phos— phoric acid is 2：1)to phenolic resin is 12％．The compressive strength of the resulting material is 1．287 MPa，density is 328 ks／m ． Key words：expanded perlite，phenolic resin，lightweight composite material，acid curing agent，properties 酚醛树脂具有耐热、耐烧蚀、阻燃、耐辐射、耐摩擦磨损等 既要保温隔热，又要具备防火阻燃性能，酚醛树脂玻化微珠轻 优异性能，广泛应用于模塑料、铸造树脂、摩擦材料、涂料、泡 质复合材料在建筑领域的发展空间巨大。 沫塑料、半导体封装材料、烧蚀材料等『l】。酚醛树脂由于合成 本课题组曾利用热压成型制各了热塑性酚醛树脂与玻化 条件以及用途不同可分为热固性酚醛树脂和热塑性酚醛树脂 微珠(闭孔珍珠岩)复合保温材料[81。本文以热固性酚醛树脂 2大类圜。酸类固化剂可使热固性酚醛树脂常温或低温固化， 作为原料，考