防水型泡沫地聚合物的制备及性能研究.pdfVIP

学兔兔 中国科技核心期刊 新癯建蟓粉拗 防水型泡沫地黯 橱碡瓣善腓 锤瓣穷 刘斯凤，徐特 (同济大学 先进土木土程材料教育部重点实验室，上海 201804) 摘要：以矿粉基地聚合物为胶凝材料，用碱性激发剂对其进行活性激发，掺入发泡剂和防水剂制成防水型泡沫地聚合物。分别 研究了3种发泡剂及其泡沫掺量、3种防水剂及其掺量对泡沫地聚合物力学强度、吸水率、导热系数和孔结构的影响。结果表明：茶 皂素发泡剂适用于该体系，泡沫的最佳掺量为1700 ml／500 g胶凝材料；BS—F液体、BS—F固体型防水剂的最佳掺量为胶凝体系的 6％，硬脂酸锌防水剂的最佳掺量为胶凝体系的4％；掺硬脂酸锌防水剂的泡沫地聚合物孔分布较为均匀，且独立不连通的闭口孑L较 多，有NT提高其防水保温性能。 关键词：泡沫地聚合物；防水；导热系数；孔结构 中图分类号：TU57+2 文献标识码：A 文章编号：1001—702X(2013)1l_0086—05 Preparation of water--proofing foam geopoly mer and study of their properties LIU Js ng，XU Te (Key Laboratory of Advanced Civil Engineering Materials of Ministry of Education，Tongii University，Shanghai 201804，China) Abstract：In this paper，water—proofing foam geopolymer were prepared by using slag—based geopolymer as binding material， and by using alkali activator to stimulate its activity and adding foaming agent and water-proofing agent．The effect of three kinds of foaming agent and their foam volume，three kinds of water-proofing agent and their dosage on the properties of foam geopolymer such as mechanical properties，water absorption，thermal conductivity and pore structure were researched respectively．Th e results showed that：Tea saponin is the better for slag-based geopolymer，the best foam volume is 1700 ml／500 g binding materia1．The best dosage of BS—F liquid and BS-F solid are 6％ of cementitious system，the best dosage of zinc stearate is 4％ of cementitious sys— tern．The pores in foam geopolymer with zinc stearate aye mostly independent and unconnected，and relatively homogeneous，its benefit for waterpr