超细矿渣粉水化反应特征及活性评价.pdfVIP

学兔兔 2016年 第 1期 (总 第 315期 ) 混 凝 土 原材料及辅助物料 Number 1 in 2016(Total No．315) Concrete MATERIAI AND ADMINICLE doi：10．3969／j．issn．1002—3550．2016．O1．023 超细矿渣粉水化反应特征及活性评价 高 嵩 。李秋义“ ，吴本清 。岳公冰“ (1．青岛理工大学a．土木工程学院．b．蓝色经济区工程建设与安全协同创新中心，山东青岛266033； 2．青岛市高新区工程质量检测有限公司，山东青岛266033) 摘 要：比较并改进流行的矿渣活性指标的测试方法，测试了超细矿渣粉的活性，并研究超细矿渣粉一水泥胶凝体系的水化机 理及水化产物。试验结果表明超细矿渣粉一水泥胶凝体系NaOH溶液浸泡养护模式激发效果最好，活性指数达到116％。XRD分 析表明超细矿渣粉一水泥胶凝体系的主要水化产物是、钙矾石。水化早期钙矾石峰随着矿粉掺入量而增强，胶凝体系的早期强 度主要来自AFt晶体结构网络。随着超细矿渣粉逐渐消耗水泥水化产生的ca(OH)：，体系后期强度主要来自超细矿渣粉在 Ca(OH)：激发下反应得到的CSH凝胶网络。 关键词：超细矿渣粉；活性指标；X射线衍射；钙矾石(AFt)；碱激发 中图分类号：TU528．041 文献标志码：A 文章编号：1002—3550(2016)01—0096—03 Hydration characteristics and activity evaluation of super fine ground granulated blast furnace slag GAO Song ，LIQiuyj ，ⅣUBenqing ，YUEGonging f 1 a．Civil Engineering Department；b．Collaborative Innovation Center of Engineering Construction and Safety in Shandong Blue Economic Zone，Qingdao Technological University，Qingdao 266033，China； 2．Qingdao High—tech District Engineering Quality Test Ltd．，Qingdao 266033，China) Abstract：The activity index measure methods were comparatively studied，the activity of super fine ground granulated blast furnace slag is hereby measured by means of improved methods，and the hydration mechanism of super fine ground granulated blast furnace slag— cement system is also studied as well as its hydration produces．The results indicate that thecement system has the highest hydration ac— tivity index of 1 16％after it was cured in the NaOH solution．The XRD analysis shows that the main hydration produces of super fine ground