粉末活性炭处理反渗透浓水的吸附模型.pdfVIP

学兔兔 第33卷第6期 土木 建 筑 与环 境 工程 Journal of Civil．Architectural Environmental Engineering Vo1．33 NO．6 2011年 12月 Dec．2011 粉末活性炭处理反渗透浓水的吸附模型 顾 平，崔航宇，赵春霞，张光辉 (天津大学 环境科学与工程学院，天津 300072) 摘 要：粉末活性炭(PAC)可显著吸附去除反渗透(RO)浓水中的COD和UV ，使其能够达标排 放或进一步资源化。首先通过正交实验选择主要吸附影响因素及其水平范围，再通过单因素实验 确定C0D和UV。 的吸附等温线和吸附动力学方程，最后通过响应曲面法(RSM)实验建立了去除 COD和UV。 的吸附模型，模型中以PAC投量和吸附时间为自变量。当PAC投量为0．9 g·L_。、 吸附时间为50 min时，COD和UV。 的RSM模型预测去除率分别为69．7 和82．4 ，实测去除 率分别为65．3 和81．8 。可见，RsM模型在设计范围内较好的预测了cOD和uV 的去除率， 能为工程实践提供全面可靠的数据基础。 关键词：反渗透浓水；粉末活性炭；吸附等温线；吸附动力学；响应曲面法 中图分类号：X703．1 文献标志码：A 文章编号：1674—4764(2011)06—0129—06 Adsorption Model of Reverse Osmosis Concentrate Treatment by Powdered Activated Carbon GU Ping，CUI Hang-yu，ZHAO Chun-xia，ZHANG Guang—hui (School of Environmental Science and Engineering，Tianjin University，Tianjin 300072， Abstract：C0D and UV254 of concentrate from reverse osmosis(RO)are removed significantly by powdered activated carbon(PAC)adsorption，which makes the effluent meet the related discharged standard or further reclamation demand． First，main adsorption factors and their Ievels were selected through orthogonal experiments．Then adsorption isotherms and adsorption kinetics equations about COD and UV254 were obtained by single factor experiments．Finally，adsorption model of COD and UV254 removal were established via response surface methodology (RSM) experiments，in which PAC dosage and adsorption time were acted as independent variables．COD and UV254 predictive removal of RSM model were 69．7％ and 82．4 respectively，and the corresponding measured values were 65．3 and 81．8 when the PAC dosage was 0．9 g·L一