紫外协同作用处理腈纶废水.pdfVIP

学兔兔 第33卷第1期 Journal of Civil。Architectural土木 建 筑 与 环Environmental Engineering境 工程 Vo1．33 No．1 2Ol1年Z月 Feb．2O11 臭氧／紫外协同作用处理腈纶废水 安 鹏，徐晓晨，杨凤林，张捍民，王明明 (大连理工大学 环境与生命学院，辽宁 大连 116023) 摘 要：论文采用臭氧／紫外(o。／uv)高级氧化技术对难生化降解且微生物毒性大的腈纶聚合工艺 废水进行处理，考察了反应时间、pH、污染物浓度等对处理效果的影响。结果表明，O。／UV协同处 理腈纶废水的效果优于臭氧和紫外单独作用效果的叠加，有明显的协同促进作用。处理后废水的 B／C由原来的0．08提高到0．3以上，可有效提高腈纶废水的可生化性，为后续的生物处理创造良 好的条件。在反应时间为30 min、pH为6的条件下，o。／UV协同作用对腈纶废水的处理效果最 佳，COD可由1 120 mg／L降解到850 mg／L，去除率达25 ，B／C可提高到0．34。降低废水中初始 污染物浓度，COD的去除率显著升高，但B／C提高不明显。 关键词：臭氧／紫外；腈纶废水；协同作用；B／C；废水处理 中图分类号：X703．1 文献标志码：A 文章编号：1674—4764(2O11)01—0135-05 Treatment of Acrylic Fiber Wastewater by Synergistic Effect of O3／uv AN Peng，XU Xiao—chen，YANG Feng-lin，ZHANG Hen—min，WANG Ming-ming (School of Environmental＆Biological，Dalian University of Technology，Dalian 116023，Liaoning，P．R．China) Abstract：Advanced oxidation processes with O3／UV are applied tO treat the acrylic fiber wastewater which is biorefractory and has high microbial toxicity．Effects of reacting time，p H value and feed concentration of contamination on the treatment efficiency are systematically investigated．The results show that，with remarkable synergistic effect，the treatment of acrylic fiber wastewater with combination of O3／UV is more efficient than the simple fold of ozone and UV treatment．The B／C of the wastewater increased from 0．08 to 0．3 after treatment，which improved the biodegradab订ity of fiber wastewater and benefits the followed— up biotreatment．The optimum treatment efficiency was achieved after 30 minutes when pH reaches 6．The COD value decreased from 1 120 mg／L to 850 mg／L，with the removd rate of 25 ，and the B／C ratio of wastewater iS increased to 0．34．