第四篇 配合物光谱(复旦大学).pdf

3.7 , , d, , , ,, , 10 3.7.1 , , * n σ * * * n π π , * ππ ππ * π , , , , , , , , 3.7.2 dd, d d , d d , , : d— d , dL 2. (term) () d— d d, () : d 1 l=2, m =±2, ±1, 0m ±1/2 l s 10 2 10D D (term) 2S1L L L l +l +l +… 1 2 3 L 0 1 2 3 4 5…. SP D F, G H … (2S1): (spin multiplicity)S (2S1) (2L1) 3 , (2S+1) = 3 (triplet) L , (2S+1) 2 (doublet) 2L (2S+1) 1 (singlet) 1L :d 2: m = +2 +1 0 –1 –2 l ↓↑ ↓↑ ↓↑ ↓ ↓ ↑ ↑ ↑ ↓ ↓ ↑ m =±1/245 s L=4, M = ±4, ±3, ±2, ±1 0, S=0