OK-不需要-讲材料的-AA型密封MH_Ni电池_Cd_Ni电池的内阻特性.pdfVIP

电 源 技 术 　 　 Chinese Journal of Power Sources 研 　究 　与 　设 　计 　 　 AA 型密封 MHNi 电池 、CdNi 电池的内阻特性 李焕春 ( 国营第七五五厂 ,河南 新乡 453069) 摘要 :研究了 M HNi 电池 、CdNi 电池在充放电过程中的内阻变化及内阻与放电电压平台的关系 。试验结果表明 ,在充 放电过程中 , 内阻变化受正负极活性物质氧化态/ 还原态的转化反应影响 ,充电过程与内压有关 。在正极中添加钴 、镉氧 化物 ,在 CdNi 电池负极中采用 PLB 新粘合剂 ,可有效地提高电池内部气体的复合性能 ,减小电池内阻。电池内阻小 ,放 电电压平台高 ,有利于延长高波放电电压的时间。 关键词 :M HNi 电池 ;CdNi 电池 ; 电池性能 ( ) 中图分类号 : TM 9 12 . 2 　　文献标识码 :B 　　文章编号 :1002087 X 200 1 030 19802 Int ernal re si st anc e p rop erty of AA size se ale d NiMH and NiCd b att ery L I Huanchun ( S tateR u n Factory N o. 755 , X i nx iang Henan 453069 , Chi na) Abstract : The variations of internal resist ance of AA size NiM H and NiCd battery during charge/ discharge cy cles were st udied as well as t he relation between internal resist ance and volt age plateau of t he battery during dis charge . The result s show t hat t he variation of internal resist ance of t he battery during charge/ discharge cycle is affected by t he t ransformation of oxidation/ reduction of active materials. Moreover , t he inner p ressure also af fectes t he internal resist ance during charge . Adding cobalt oxide and cadmium oxide into po sitive elect rode and using PLB binder in negative of t he NiCd battery will effectively increase t he p roperties of t he inner gas recom bination and reduce t he internal resist ance of t he battery . Lower