气相分子吸收光谱法测定印染废水中氨氮的影响因素.pdf

第 9 卷 第 1期 环境监控与预警 Vol . 9,No . 1 2017年 2 月 Environmental Monitoring and Forewarning February 2017 气相分子吸收光谱法测定印染废水中氨氮的影响 因素 刘琳娟，李丽，汤春艳，胡小玲，纪灵娴 (南通市环境监测中心站，江 苏 南 通 226006) 摘 要 ：采用气相分子吸收法光谱测定印染废水中的氨氮，并对相关影响因素进行探讨。结果证实，硫化物和尿素会对氨 氮的测定产生负干扰，硫化物干扰可用乙酸锌-乙酸钠固定液沉淀法去除，尿素干扰可以用稀释法去除，但仅适用于氨氮 质量浓度〇. 1〇 mg /L 且稀释后尿素质量浓度€ 100 mg /L 的水样；苯胺、浊度和色度对测定无干扰，可直接检测。 关键词：气相分子吸收光谱法；印染废水；氨氮；影响因素 中图分类号：X832;0657.7 文献标志码： B 文章编号：1674 - 6732 (2017 ) 01 - 0038 - 04 Determination of Ammonia Nitrogen in Printing and Dyeing Wastewater by Gas Phase Mo­ lecular Absorption Spectrometry LIU Lin -juan , LI L i， TANG Chun -yan , HU Xiao -ling , JI Ling-xian {Nantong Environmental Monitoring Center Station ，Nantong， Jiangsu 226006 , China ) Abstract ：Gas phase m olecular absorption spectrom etry was adopted to determ ine the am m onia nitrogen in printing and dyeing w astew ater, and the related influencing factors were discu ssed. R esults confirm th a t, in printing and dyeing w astew ater, sulfide and urea produce negative interference. The sulfide interference can be rem oved by zinc acetate and sodium acetate precipitation m eth­ o d , w hile the urea interference can be rem oved by dilution m ethod. But the dilution m ethod is only suitable for the w ater sam ple with the concentration of am m onia nitrogen m ore than 0. 10 m g /L and the concentration of u rea less than 100 m g /L after dilution. A ni­ line , turbidity and colority don^ interfere with the determ ination. Key words ：G as-phase m olecular absorption sp ectro m etry ；Printing and dyeing w astew ater ；A m m onia n itro g e n ；Influence factor 水中的氨氮主要来源于生活污水中含氮有机 1 实验部分 物的微生物分解、某些工业废水及农田排水等，可