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热力学双语练习
1) one mole of a monatomic ideal gas in the initial state T=273K, P=1atm, is
subject to the following three processes, each of which is conducted reversibly.
a. a doubling of its volume at constant pressure
b. Then a doubling of its pressure at constant volume
-4 2
c. Then a return to the initial state along the path p=6.643*10 V +0.6667
Calculate the heat and work effects, which occur during each of the process.
Solution: a)2.27kJ; b )0J; c )-0.0149J
2) The initial state of a quantity of monatomic ideal gas is P=1atm V=1liter and
T=373K. The gas is isothermally expanded to a volume of 2 liters and is then
cooled at constant pressure to the volume V. this volume is such that a reversible
adiabatic compression to a pressure of 1 atm returns the system its initial state.
All of the changes of state are conducted revisable adiabatic. Calculate the total
work done on or by the gas
Solution: 1.3J
3)two moles of a monatomic ideal gas are at contained at a pressure of 1 atm and
temperature of 300K, 34.166j of heat are transferred to the gas as a result of
which the gas expands and does 1216 joules of work against its surroundings.
The process is reversible. Calculate the final temperature of the gas.
Solution: 252.5K
4)one mole of N gas is contained at 273 K and a pressure of 1 atm. The addition
2
of 3000 joules of heat to the gas at constant pressure causes 832 joules of work to
be done during the expansion*(. Calculate (a) the final state of the gas, (b) the
value of △U and △H for the change of state. And (c) the values of CV for N2 .
Assume that nitrogen behaves as an ideal gas. and that the above change of state
is conducted reversibly.
Solution: a)P=1atm, T=373K, V=30.6L; b)
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