Sb在Al-Si合金中的变质行为.pdfVIP

维普资讯 学兔兔 Mar．2008 铸 造 VOI．57 No．3 FOUNDRY Sb在Al—Si合金中的变质行为 董光明 ，廖恒成 ，孙国雄 ，韩正同z (1．东南大学材料科学与工程学院，江苏南京210018；2．中国矿业大学机电工程学院，江苏徐州221008) 摘要：sb的变质机理可分为影响形核理论与限制生长理论。影响形核理论又分为增加形核核心及减少形核核心二种 假说。限制生长理论包括sb降{ff~Si的扩散能力假说、共晶si被共晶Al超越假说、AISb分子的吸附阻碍共晶si生长假说、 sb质点阻碍共晶si生长假说、sb在固液界面富集假说、sb吸附在共晶si的表面阻碍共晶si生长假说等。sb变质的A1．Si 合金共晶反应倾向于以体积凝固的方式进行。AISb及Mg Sb：是共晶形核的可能核心。Sb会降低A1．Si合金的共晶反应温 度。纯Sb变质有50min孕育期。Mg对Sbt~／变质有干扰作用。Sb的含量较高时会出现过变质现象。 关键词：锑；A1．Si合金；变质 中图分类号：TG146．2 1 文献标识码：A 文章编号：1001—4977(2008)03—02ll一04 Modifying Effect of Antimony in AI-Si Alloys DONG Guang-ming’一，LIAO Heng-cheng’，SUN Guo-xiong’，HAN Zheng-tong (1．School of Material Science and Engineering，Southeast University，Nanjing 21 001 8，Jiangsu China；2．School of Mechanical and Electrical Engineering．China University of Mining and Technology，Xuzhou 221 008，Jiangsu，China) Abstract： Modification mechanism of Al-Si alloys by antimony can be classified as two kinds： nucleation hypothesis and growth hypothesis．The nucleation hypothesis includes nuclei increment theory and nuclei decrease theory．The growth hypothesis includes theory of Sb decreasing the confusion ability of silicon atom．theory of eutectic aluminum leading eutectic silicon．theory of adsorption of AISb on eutectic silicon，theory of restriction of pure antimony particles，theory of antimony atom enrichment in fr0nt of inter『ace．theory of absorption of antimony atoms on eutectic silicon SUdace．The eutectic reaction of A1．Si alloys modified by antimony iS apt to solid in a mushy mode．AlSb and MgsSb2 are po