不同分散剂对SiC泡沫陶瓷水基浆料性能的影响.pdfVIP

学兔兔 Feb．2016 VOI．65 NO．2 不同分散剂对SiC泡沫陶瓷水基浆料性能的影响 黄 晶，张军战，张 颖，石 鑫 (西安建筑科技大学，材料与矿资学院，功能材料研究所，陕西西安710055) 摘要：采用聚乙二醇、硅酸钠、羧甲基纤维素钠3种分散剂分别制备了碳化硅泡沫陶瓷浆料，通过浆料的粘度与沉 降实验考查了分散剂的种类、含量以及pH值对碳化硅浆料流变性及稳定性的影响。结果表明，当PEG~INa SiO，的含 量分别为0．6％和0．4％时，SiC浆料的粘度最低，流动性与稳定性最好；pH值对浆料的流动性和稳定性影响显著，当 pH为10时，SiC浆料的流动性与稳定性最好；以0．2％的CMC作为分散剂，当pH值为10时，固相体积分数为65％时可 制得性能良好的浆料，此时浆料呈现较强的触变性。 关键词：分散剂；SiC浆料；流变性；稳定性 中图分类号：TG223 文献标识码：A 文章编号：1001—4977(2016)02—0175—05 I nfluence of Different Dispersants on Properties of Aqueous Slurry of SiC FOam Ceramics HUANG Jing，ZHANG Jun—zhan，ZHANG Ying，SHI Xin (Ftmction Materials Institution，College ofMaterialsMineral Resources，Xi’an University of Architecture and Technology，Xi’an 710055，Shaanxi，China) Abstract：Three kinds ofdispersing agents were used in the preparation ofsilicon carbide foam ceramic slurry, including PEG，Na2SiO and CMC，respectively．The effects ofthe type，content of dispersant and pH value on the rheological properties and stability of silicon carbide slurry were characterized by viscosity and sedimentation experiment．The results show that the slurry could have good stability and rheological properties when the content ofPEG is 0．6 wt％and Na，SiO is 0．4 wt％．The effects ofpH value on the rheological behavior and stability ofthe slurry are significant．the slurry with 0．2 wt％CMC。PH value 1 0 and solid COntent 65％have good performance，and it presents strong thixotropy． Key words：dispersant；SiC slurry；rheological behavior；stability SiC泡沫陶瓷因其优异的高温强度、抗热震和耐腐 化硅泡沫陶瓷的孔筋结构致密，抗热震性能优良，导 蚀性，成为铸造中重要的过滤器，并引起国内外的广 电特性发生变化。Bao 采用前驱体转换法，用连通 泛关注[ 。目前，有机泡沫浸渍工艺已经成为生产熔 气孔的聚氨酯泡沫浸渍聚碳硅烷 (P