超声化学原位合成(AI2O3+AI3Zr)p／A356复合材料.pdfVIP

维普资讯 学兔兔 铸 造 Apr．2008 · 354· FOUNDRY Vo1．57 NO．4 超声化学原位合成 (AI2O3+AI3Zr)p／A356复合材料 Th．善，赵玉涛，张松利，陈 刚 (江苏大学材料科学与工程学院，江苏镇江212013) 摘要：采用熔体反应法，以A356．Zr(CO )：为反应体系，并在反应过程中施加高能超声，超声化学原位合成了 (A1 O3+A13Zr；Ip／A356~合材料。扫描电镜 (SEM)与x衍射 (XRD)分析表明：生成的颗粒为Al203和A13Zr，颗粒细小， 形状一致，且弥散分布于铝基体中；试验发现：在相同反应条件下，与常规原位反应相比，超声作用下反应更快、更 完全，缩短了反应时间，并从反应动力学角度进行了分析。复合材料的力学性能研究表明：经过超声处理的复合材料 的抗拉强度达到了391 M．Pa，比未加超声的提高了23％。拉伸断口形貌分析表明：在超声作用下，复合材料断口上韧窝 数量明显增加，韧窝变小、变深，材料韧性断裂特征明显。 关键词：高能超声；原位反应；铝基复合材料；力学性能 中图分类号：TB33 l 文献标识码：A 文章编号：1001—4977(2008)04—0354—05 Synthesized(AI2O3+AI3Zr)p／A356 Com posites Via I n—Situ U ltrason ic—Chem istry Reaction DING Jia·shan，ZHAO Yu·tao，ZHANG Song-li，CHEN Gang (School of Materials Science and Engineering，Jiangsu University，Zhenjiang 21 201 3， Jiangsu，China) Abstract：AI： r and AI203 particles reinfolrced aIuminum matrix composites have successfully been synthesized using direct melt reaction method via in-situ ultrasonic．chemistry reaction in the system A356．Zr(CO3)2．With the help of scanning electron microscope(SEM)and X-ray diffraction(XRD)， it was found that that the AI3zr and AI203 particulate phases with same shape are produced，and these particles are fine and wel1．distributed in aIuminum matrix． At the same time． ultrasonic．chemistry reaction in AI melt iS much faster and more complete than traditionaI in．situ reaction．The results of the mechanicaI property test showed that the tensile strength of (AI2O3+AI3zr)JA356 composites treated by high intensity ultrasonic was higher by neady 23％th