废柴油机油絮凝抽提精制工艺-学兔兔 www.xuetutu.com.pdfVIP

学兔兔 石 油 化 工 PETR0CHEMICAL TECHN0L0GY 2013年第42卷第2期 废柴油机油絮凝抽提精制工艺 李瑞丽，齐羽佳 (中国石油大学(北京)重质油国家重点实验室，北京 102249) [摘要]采用絮凝抽提法对4s店回收的废柴油机油进行了再生利用研究。分别用异丙醇、丁酮两种单一溶剂，考察了精制温 度、精制时间、剂油比(溶剂与废柴油机油的质量比)对精制油收率及性质的影响，得到最佳精制条件为：精制温度4O℃， 精制时间30 min，异丙醇的剂油比3，丁酮的剂油比5。在最佳精制条件下，异丙醇精制 由的收率只有27．99％；而丁酮精制油 的收率达到92．68％，但精制油的质量差。将异丙醇和丁酮混合作为复合溶剂，在精制温度4O℃、精制时间30 min的条件下， 考察了复合溶剂配比、剂油比等因素的影响。实验结果表明，复合溶剂的最优配比为m(丁酮)：m(异丙醇)=3、最佳剂油比 为3。复合溶剂精制油经白土补充处理后的油品符合HVI400基础油的标准，收率达65．77％。 [关键词]废柴油机油；精制；絮凝抽提；基础油 [文章编号]1000—8144(2013)02—0222—08 [中图分类号]TE 626．32 [文献标志码]A Flocculation-Extraction of Waste Diesel Engine Oil for Base Oil Li Ruili，Oi Yujia (State Key Laboratory ofHeavy Oil Processing ofChina University ofPe~oleum(Beijing)，Beijing 102249，China) l Abstract j Waste diesel engine oil was refined by flocculation—extraction with isopropanol and／ or butanone as solvents．The effects of extraction temperature，extraction time and the mass ratio of solvent to the waste oil on the yield and quality of the refined oil were researched．The experimenta1 results showed that under the conditions of extraction temperature 40 ，extraction time 30 min． and the mass ratios of solvent to the waste diesel engine oil 3 for isopropanol and 5 for butanone，the refined oil yield were 27．99％ and 92．68％respectively．But when butanone was used as the solvent． the quality of the refined oil was not good．A composite solvent is composed of isopropanol and