CeO_2催化剂在水煤气变换反应中的活性-学兔兔 www.xuetutu.com.pdfVIP

学兔兔 石 油 化 工 2013年第42卷第7期 PETR0CHEMICAL TECHN0LOGY ·717· CuO／CeO2催化剂在水煤气变换反应中的活性 邹 月，廖卫平，金明善，索掌怀 (烟台大学 应用催化研究所，山东 烟台 264005) [摘要]采用共沉淀法、沉积沉淀法和等体积浸渍法制备TCuO／CeO：催化剂，考察了cuQ负载量和H 还原温度对该催化剂水 煤气变换反应活性的影响。采用XRD、N 吸附、uV—Vis DRS、TEM、H：一TPR技术对催化剂进行了表征。实验结果表明，共 沉淀法制备的20％(W)CuO／CeO 催化剂在200℃下还原后表现出较高的水煤气变换反应活性，反应温度250℃时CO转化率为 19．6％。CuO在催化剂中或高度分散在载体表面，或以大颗粒形式存在，还原后生成活性组分Cu20和Cu。。CuO与CeO，之间的 强相互作用能阻止CuO颗粒聚集，降低其还原温度；但过度还原会破坏这种相互作用，使催化剂活性降低。 [关键词]氧化铜／氧化铈催化剂；共沉淀法；水煤气变换反应 [文章编号]1000—8144(2013)O7～0717—07 [中图分类号]TQ 426．82 [文献标志码]A Activity of CuO-CeO2 Catalyst in Water-Gas Shift Reaction Zou Yue，Liao Weiping，JinMingshan，SuoZhanghuai (Institute ofApplied Catalysis，Yantai University，Yantai Shandong 264005，China) l Abstract J CuO／CeO2 catalysts were prepared by CO—precipitation，deposition—precipitation and wetness impregnation methods，and characterized by means ofN2 adsorption，XRD，ug-vis DRS， TEM and H2-TPR．The effects of the preparation method，CuO loading and reduction temperature on the activity of the CuO／CeO2 catalysts in water—gas shift(WGS)reaction were investigated．The results show that，after reduced at 200 oC by H2，the activity of 20％(w)CuO-CeO2 catalyst prepared by CO—precipitation method is the hi ghest．the CO conversion of 1 9．6％ at 250 oC．In the unreduced catalyst，CuO either highly disperses on CeO2 surface or exists in the form of large grains．In the reduced and used catalysts，most of CuO is reduced into Cu20 and Cu。which are considered as the active sites in WGS reaction．The strong interaction between CuO and CeO2 can inhibit the aggregation