CO2氧化低碳烷烃脱氢制低碳烯烃-学兔兔 www.xuetutu.com.pdfVIP

学兔兔 石 油 化 工 2010年第39卷第4期 PETR0CHEⅣⅡCAL TECHNOLOGY ·359· l特约述评l CO2氧化低碳烷烃脱氢制低碳烯烃 乐英红，华伟明 (复旦大学 化学系 上海市分子催化和功能材料重点实验室，上海 200433) [摘要]对近年来国内外关于CO2氧化低碳烷烃脱氢制低碳烯烃的研究成果进行了综述。CO 作为温和的氧化剂应用于低碳烷 烃氧化脱氢可提高反应的平衡转化率，抑制催化剂失活，是一个有应用前景的新工艺。用于此类反应的催化体系主要有cr系和 Ga系，但这两类催化剂的稳定性较差，通过调变催化剂载体表面的性质来改变活性组分与载体问的相互作用，可以提高催化剂的 稳定性。不同催化体系中CO2的作用机制不同，cr系催化剂上主要为氧化还原机理，而Ga系催化剂上则为异裂机理。为进一步 提高反应效率，探索和研究同时具有脱氢与活化C02能力的新催化体系是发展方向。 [关键词]低碳烷烃；氧化脱氢；低碳烯烃；二氧化碳；铬系催化剂；镓系催化剂 [文章编号]1000—8144(2010)04—0359—07 [中图分类号]TQ 211 [文献标识码]A Oxidative DehydrOgenatiOn of Light Alkanes with CO2 to Olefins Yue Yinghong，Hua Weiming (Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials，Depa~nent of Chemistry Fudan University，Shanghai 200433，China) [Abstract j CO2 can be utilized as a mild oxidant in dehydrogenation of alkanes to olefins． Equilibrium conversion of the dehydrogenation can be increased and deactivations of the catalysts can be suppressed by adding CO2．Dehydrogenation of fight alkanes to their corresponding olefins in the presence of CO2 has been reviewed，including the recent advances in development of the catalysts for the dehydrogenation，especially chromium—based and gallium—based catalysts．The main problems are that stability of these catalysts is still rather poor and their activity declined dramatically with reaction time， which are fatal for meir industrial application．Improvements for the stability have been made recently by changing interaction between ac