流场流分离技术在聚合物相对分子质量分布及微粒分布测定中的应用-学兔兔 www.xuetutu.com.pdfVIP

学兔兔 石 油 化 工 2012年第41卷第1期 PETR0CHEMICAL TECHNOLOGY ·9· 流场流分离技术在聚合物相对分子质量分布及 微粒分布测定中的应用 罗春霞，侯家祥，张龙贵，郭梅芳，乔金棵 (中国石化 北京化工研究院，北京 100013) [摘要]场流分离作为一种新的分析技术，逐渐被用来分离和表征聚合物、生物大分子和聚合物微粒。介绍了作为场流分离技 术之一的流场流分离(F1FFF)技术的原理。重点综述了常温F1FFF技术在聚电解质等水溶性聚合物及聚合物乳胶粒水分散体 系的分离和表征中的应用，以及高温F1FFF技术在高相对分子质量聚烯烃的分离和表征中的应用。讨论了F1FFF技术相对于 GPC技术的优势及目前存在的问题，指出了F1FFF技术在高相对分子质量聚合物分析中的应用前景。 [关键词]场流分离；流场流分离；相对分子质量分布；聚合物；微粒 [文章编号]1000—8144(2012)O1—0009—010 [中图分类号]TQ050．4 [文献标识码]A Application of Flow Field—Flow Fractionation Techniques to the Characterization of Relative Molecular Mass Distribution and Particle Size Distribution of Polymers Luo Chunxia，Hou Jiaxiang，ZhangLonggui，Guo Meifang，Qiao Jinliang (SINOPEC Beijing Research Institute ofChemical Industry，Be~mg 100013，China) [Abstract]As a new kind of analytical technique，field—flow fractionation has been developed specifically for separating and characterizing polymers，biomacromolecules and polymer particles．The principle of flow field—flow fractionation(FlFFF)as a kind of field flow fractionation are introduced． Application of F1FFF to the separation and characterization of water-soluble polymers such as polyelectrolyte and polymer latex in aqueous system at room temperature and application of F1FFF to the separation and characterization of polyolefins with high relative molecular mass at high temperature are reviewed．Both the advantages of F1FFF compared to GPC and the problems in F1FFF are discussed．The future application of F1FFF to polymers with high relative molecular mass is discussed． [Keywords]field—flow fractionation；flow field．flow fractionation；