甲醇制丙烯产品气分离工艺的开发-学兔兔 www.xuetutu.com.pdfVIP

学兔兔 石 油 化 工 2015年第44卷第3期 PETROCHEMICAL TECHN0LoGY ·273· 甲醇制丙烯产品气分离工艺的开发 王子宗 ，刘洪谦 ，王基铭 (1．中国石油化工集团，北京 100029；2．中国石化工程建设有限公司，北京100101) [摘要]针对甲醇制丙烯(MTP)反应产物的特点，对MTP产品气分离工艺进行了研究和改进。在前脱丙烷流程的基础上，采 用双塔脱丙烷工艺降低脱甲烷塔负荷，用中冷中压脱甲烷塔对乙烯进行初步回收，用中冷油吸收回收脱甲烷塔尾气中的乙 烯，用分凝分馏塔与膨胀机组合回收尾气中夹带的吸收剂和少量乙烯，采用高度 “热集成”的脱乙烷塔和乙烯精馏塔。以1．7 Mt／a MTP装置产品气压缩机进料为基准，通过对前脱丙烷流程进行流程组合和操作参数优化，能使产品气压缩机轴功率消耗 降至6 738 kW，丙烯压缩机轴功率消耗降至3 529 kW，离开分离工段的尾气中乙烯和吸收剂含量接近痕量，分离部分乙烯收 率达到99．67％。 [关键词]甲醇制丙烯；产品气分离；乙烯；丙烯；工艺开发 [文章编号]1000—8144(2015)03—0273．06 [中图分类号]TQ 221．21 [文献标志码]A A NewApproachforRecovering EthyleneinMixed GasfromMethanolto PropyleneProcess WangZizong ，LiuHongqian ，WangJiming (1．China Petrochemical Corporation，Beijing 100029，China；2．S1NOPEC Engineering Incorporation，Beijing lOOlO1，China) [Abstract~Based on characteristics of the products from methanol to propylene(MTP)process， approaches for the recovery of ethylene in the MTP product gas were studied．In the mature front—end depropanizer process， twin depropanizer process was adopted to reduce the demethanizer load， medium·-cold and medium--pressure demethanizer were employed for the preliminary recovery of ethylene，and medium—cold oil absorbing process was utilized to recycle ethylene in the demethanizer tail gas．The absorbent and ethylene entrained in the tail gas were recovered by the combination of condensing fractionating tower and expande~The integration of deethanizer tower and ethylene splitter was employed．The actual shaft power consumption of the product gas compressor was reduced to 6 738 kW， the shaft