高抗冲共聚聚丙烯的结构与性能-学兔兔 www.xuetutu.com.pdfVIP

学兔兔 石 油 化 工 2015年第44卷第7期 PETR0CHEMICAL TECHN0LOGY ·877· 料 高抗冲共 聚聚丙烯的结构与性能 祖风华，李荣波，王 莉，义建军 (中国石油 石油化工研究院，北京 100195) [摘要]利用升温淋洗分级技术对两种抗冲共聚聚丙烯保险杠专用料 (M1和M2)进行了分级，并采用”C NMR和GPC等方法 对试样及各级分进行了组成分布、分子序列结构分布、相对分子质量及其分布的研究。表征结果显示，M1和M2主要由乙丙 无规共聚物、乙丙嵌段共聚物及丙烯均聚物组成，M2的35℃以下和100 以上可溶级分的含量较M1高。M1的[PE](P为丙 烯单元、E为乙烯单元)二元序列结构和[PPE]，[EPE]，[EEP]，[PEP]三元序列结构的总含量均低于M2。M1与M2的主要 级分为l1O℃可溶级分，含量超过30％(w)以上。M2的室温可溶级分和l1O℃以上高温可溶级分的相对分子质量明显高于M1 的对应级分，故M2具更好的综合性能。 [关键词]高抗冲共聚聚丙烯；升温淋洗分级；聚丙烯 [文章编号]1000—8144(2015)07—0877—05 【中图分类号]TQ 325．14 [文献标志码]A Structure and Properties of High Impact Ethylene—Propylene Copolymer ZuFenghua，LiRongbo，WangLi，YiJianj“n (Petrochina Petrochemical Research Institute，Beijing 100195，China) [Abstract]The chemical compositions of two impact ethylene—propylene copolymers(M l，M2) were investigated by means of preparative temperature rising elution fractionation(TREF)and“C NMR．Their composition distributions．chain structures and fractions were analyzed by means of TREF and GPC．The results showed that M1 and M2 mainly consisted of random ethylene—propylene copolymer，a small amount of block ethylene—propylene copolymer and homo—polypropylene．The preparative TREF showed that the major fractions in the two samples were F．110 and the contents of F—ll0 were more than 30％(w)．The M2 sample contained more soluble fractions in the temperature range(1ower than 3 5 or higher than 1 O0℃)than M 1．The total content of two．membered and three-membered sequence structures in M 1 were less than tha