1,2-二甲苯基二氮烯的合成、单晶培养及结构解析-毕业论文(设计).docxVIP

泰 山 学 院本科毕业论文1,2-二甲苯基二氮烯的合成、单晶培养及结构解析所 在 学 院 化学与化工学院 专 业 名 称 化 学 申请学士学位所属学科 理 学 年 级 二〇一二级 学生姓名、学号指导教师姓名、职称 王 平 教授 完 成 日 期二〇一二年五月摘要醛、酮等具有活泼α-H的化合物（酸、酯、硝基化合物、氰基化合物、末端炔烃…）与甲醛、胺（一级胺、二级胺或氨）在乙醇溶液中回流，使酮的α-H被胺甲基取代。该反应也称为胺甲基化反应，所的产物成为曼尼希（Mannich）碱。曼尼希碱（Mannich base）和2-甲基苯胺和衍生物浓时具有强烈的粪臭味，扩散力强而持久；高度稀释的溶液有香味，可以作为香料使用。从而引起了人们对该类化合物的浓厚兴趣并进行了深入的研究。而2-甲基苯胺衍生物中的NH结构有三阶光学非线性，已经成为光学领域的研究热点。本实验以苯甲醛、2-甲基苯胺与丙酸反应,以钼酸铵为催化剂，在石蜡浴并在搅拌条件下回流合成新的化合物，采用溶剂蒸发法在真空干燥箱内28oC的恒定温度下对该化合物进行了单晶培养，并获得了其单晶；采用X-射线单晶衍射对其晶体结构进行了解析。关键词：曼尼希碱，三阶光学非线性，金属配合物ABSTRACTAldehydes and ketones is lively and alpha Hcompounds (acid, esters, nitrocompounds, p-cyanic-benzyl compounds etc. With formaldehyde, amine (level 1, level 2 amine or amine ammonia in ethanol solution), make the backflow testosterone alpha H was amine methyl replaced. This reaction is also called amine methylation, the product of the reaction was named Mannich alkali.Mannich base and 2-p-trifluoromethylaniline and derivatives thick with a strong odor of dung, diffusion of strong power and lasting;Highly diluted solution have fragrance, can be used as a flavoring. This arrised the people with the strong interest in this kind of compounds and studied. And 2-p-trifluoromethylaniline derivatives of NH possess third-order nonlinear optical properties, and has become a hot spot of research in the field of optics.In this experiments, we performed Mannich reaction using benzaldehyde, 2-p-trifluoromethylaniline and propionic acid as reactantand molybdate as catalyst and obtained a new compound. Using solvent evaporation method we grown the single crystals of the compound and determinedits crystal structure by means of X-ray single crystal diffraction.Key words: Mannich base, third-order nonlinear optics,metal complexes目 录1引 言--------------------------------------------------------------11.1 曼尼希反应的发展及曼尼希碱的应用---------------------------------11.2 曼尼希反应的操作选择--