加氢脱硫CoMo／AI2O3催化剂的原位FTIR表征-学兔兔 www.xuetutu.com.pdfVIP

学兔兔 石 油 化 工 · 790· PETROCHEMICAL TeCHN0L0GY 2014年第43卷第7期 加氢脱硫CoMo／AI2O3催化剂的原位FTIR表征 方玉晨 一，马 波 ，孙万付 ，凌凤香 ，王少军 ，赵国利 (1．中国石化 抚顺石油化工研究院，辽宁 捌顷113001；2．辽宁石油化工大学 石油化工学院，辽宁 抚顺 113001) [摘要]采用等体积浸渍法制备TMo／y—A1 O，和CoMo／y—A1：O 硫化态催化剂，利用原位FTIR方法对催化剂吸附CO前后的结 构进行了表征，分析了催化剂活性中心的变化规律。表征结果显示，Mo／y—A120 催化剂中存在未改性的MoS：吸附相；CoMo／ Y—AI：O 催化剂中由于加入了助剂co，可使部分MoS：相转变为CoMoS相，且分散度较高；CoMoS相的形成可增加催化剂活性 位的数量、提高催化剂的加氢脱硫(HDS)活性。当CoO-~量为3．1％(w)时，CoMo／y—A1 O，催化剂对4，6-二甲基二苯并噻吩的 HDS活性最高，达到56％。 [关键词]钻钼／Y一氧化铝催化剂；原位傅里叶变换红外光谱；一氧化碳吸附；硫化；加氢脱硫 [文章编号]1000—8144(2014)07—0790—05 [中图分类号]TQ426．82 [文献标志码]A In Situ FTIR CharacterizatiOn of CoMo／AI2O3 Catalyst for Hydrodesulfurization Fang Yuchen 一，MaBo ，Sun Wanfu ，LingFengxiang ，WangShaojun ，Zhao Guoli (1．SINOPEC Fushun Research Institute ofPetroleum and Petrochemicals，Fushun Liaoning 113001，China； 2．Institute ofPe~o-ChemicalTechnology，Liaoning ShihuaUniversity，FushunLiaoning 113001，China) [Abstract]Sulfurized Mo／7一AI2O3 and CoMo／7一A12O3 catalysts were prepared by all impregnation method．The adsorption of CO on the catalysts was studied by means of in—situ FTIR and the change of active sites was analyzed．The results showed that there was tin—modified MoS2 phase in the sulfurized Mo／y—A1203 catalyst；with the addition of Co，part of MoS2 phase in the sulfurized CoMo／7一A12O3 catalysts could be transformed into CoMoS phase with high dispersion，which could increase the amount of active sites and the activity of the catalyst in hydrodesulfurization(HDS)．The activity of the sulfurized CoMo／y—A1203 catalyst with the CoO content of 3．1％(w)in HDS for the removal of dimethyl dibenzothiophene was