SiO2的表征及其在乙酸乙酯加氢合成乙醇中的催化性能-学兔兔 www.xuetutu.com.pdfVIP

学兔兔 石 油 化 工 2013年第42卷第6期 PETROCHEMICAL TECHNOLoGY ·615· Cu／SiO2的表征及其在乙酸乙酯加氢合成 乙醇中的催化性能 雷陈明，顾顺超，阎建民，肖文德 (上海交通大学 化学化工学院，上海 200240) [摘要]采用尿素均匀沉淀法制备了Cu／SiO 催化剂，用H 一TPR、XRD和N：吸附-脱附等技术对其进行了表征；将Cu／SiO 催化 剂用于催化乙酸乙酯加氢制备乙醇的反应，考察了反应温度、反应压力、反应物配比和液态空速对乙酸乙酯加氢反应活性和 选择性的影响。表征结果显示，Cu／SiO：催化剂具有较大的比表面积和较低的起始还原温度。实验结果表明，适宜的反应条件 为：反应温度220 oC、反应压力3．0 MPa、氢气与乙酸乙酯的摩尔LL60、液态空速1．0 h～，在此条件下，乙酸乙酯转化率可达 96．2％，乙醇选择性为97．8％。 [关键词]铜，二氧化硅催化剂；均匀沉淀法；乙酸乙酯；加氢；乙醇 [文章编号]1000—8144(2013)06—0615—05 [中图分类号]TQ426 [文献标志码]A CharacterizatiOn of Cu／SiO2 Catalyst and Its Performance in HydrOgenatiOn of Ethyl Acetate to Ethanol LeiChenming，GuShunchao，YanJianmin，Xiao Wende (School ofChemistry and Chemical Engineering，Shanghai Jiao Tong University，Shanghai 200240，China) [Abstract]A Cu／SiO2 catalyst was prepared by a homogeneous precipitation method with urea as the precipitant，characterized by means of H2一TPR，XRD and BET，and used in the hydrogenation of ethyl acetate to ethano1．The effects of temperature，pressure，mole ratio of H2 to ethyl acetate and LHSV on the activity and selectivity of the catalyst were investigated．The results show that the catalyst has high specific surface area and low initial reduction temperature．The catalyst performance in the hydrogenation reaction was evaluated．Under the optimal reaction conditions of temperature 220 ． pressure 3．0 MPa，n(H2)：n(ethyl acetate)60 and LHSV 1．0 h～，the conversion of ethyl acetate and the selectivity to ethanol reached 96．2％and 97．8％．respectively． [Keywords]copper／silica catalyst；homogeneous precipitation；ethyl ace