一种疏水缔合聚合物稠化剂的合成及压裂液性能评价.pdfVIP

学兔兔 石 油 与 天 然 气 化 工 第44卷 第4期 CHEMICAL ENGINEERING OF 0IL GAS 93 一 种疏水缔合聚合物稠化剂的合成及压裂液性能评价 何坤忆 罗米娜 钟 尧 秦紫薇 西南石油大学化学化工学院 摘 要 以AM、AMPS和阳离子疏水单体MD一18为单体，采用水溶液自由基聚合法合成了疏水 缔合聚合物压裂液稠化荆HAPAM一18。研究了HAPAM一18的增黏性能、与表面活性剂的相互作用以 及压裂液体系的相关性能。结果表明，HAPAM一18的表观黏度随质量浓度增加而增大，临界缔合浓度 为0．15 g／L；HAPAM-18与表面活性剂的相互作用符合三阶段模型，且 SDBS与HAPAM一18的相互 作用强于CTAB；p(HAPAM-18)0．6 g／L+ C(SDBS)0．5 mmol／L+p(KC1)2 g／L配制的压裂液体系 的耐温性能达到101℃。耐剪切性实验和动态频率扫描表明，该压裂液体系具有良好的耐剪切性和黏 弹性；过硫酸铵能使压裂液彻底破胶，破胶液残渣含量低至未检出，该压裂液是一种清洁压裂液。 关键词 疏水缔合聚合物 稠化剂 表面活性剂 清洁压裂液 中图分类号：TE357．1 1 文献标志码：A DOI：10．3969／j．issn．1007—3426．2015．04．019 Synthesis of a hydr0ph0bically associating polymer thickening agent and evaluation of the fracturing fluid properties He Kunyi，Luo Mina，Zhong Yao，Qin Ziwei (College of Chemistry and Chemical Engineering，Southwest Petroleum University，Chengdu 610500，China) Abstract：A hydrophobically associating polymer thickening agent HAPAM一1 8 for fracturing fluid was synthesized by the aqueous solution free—radical copolymerization of AM，AMPS and a cationic hydrophobic monomer MD一18．The thickening ability and interactions with surfactant of HMPAM一18 were studied as well as the fracturing fluid properties．Result shows that the apparent viscosity of HAMPAM-1 8 solution increased with increasing concentration and its critical aggregation concentra— tion is 0．15 g／L．The interactions between HAPAM-18 and surfactants fitted the three stage model and the interactions between HAPAM一1 8 and SDBS iS more intensive than that with CTAB．The frac— turing fluid system composed of 0．6 g／L HAPAM一18+ 0．5 mmol／L SDBS+2 g／L KC1 reached a temperature resistance of 101 C and showed