丁e-V共掺杂TiO2高性能吸附剂的制备与表征-学兔兔 www.xuetutu.com.pdfVIP

学兔兔 石 油 化 工 · 212· PETROCHEMICAL TECHN0LOGY 2011年第40卷第2期 Fe—V共掺杂TiO2高性能吸附剂的制备与表征 谢丽珊，颜桂炀，郑柳萍，潘青山 (福建师范大学 化学与材料学院，福建 福州 350007) [摘要]通过溶胶凝胶法、水热法和共沉淀法，分别以钛酸丁酯、异丙醇钛、硫酸钛、四氯化钛为钛源合成了一系列Fe—v共掺杂 的纳米TiO2吸附剂，研究了钛源、制备方法及煅烧温度对吸附剂吸附效果的影响，并采用XRD，SEM，EDX，TG—DTA，FrIR等手 段分析了吸附剂的结构。实验结果表明，Fe—V共掺杂明显提高了TiO2的吸附活性，其中以四氯化钛为钛源、通过共沉淀法制 备、350℃焙烧处理的Fe—V共掺杂TiO2具有最佳的吸附活性，30 min内对质量分数1．0×10 I5亚甲基蓝的脱色率可达97％以 上；该吸附剂循环使用8次仍具有较高的吸附性能，且四氯化钛为较廉价的钛源，因此该高效吸附剂具有良好的工业应用前景。 [关键词]共沉淀法；铁一钒共掺杂二氧化钛吸附剂；吸附；四氯化钛 [文章编号]1000—8144(2011)02—0214—05 [中图分类号]TQ 426．6 [文献标识码]A Preparation and Characterization of Fe-V Codoped TiO2 Adsorbent with High Adsorbility Xie Lishan，Yan Guiyang，Zheng Liuping，Pan Qingshan (College of Chemistry and Materials Science，Fujian Normal University，Fuzhou Fujian 350007，China) [Abstract] Fe—V codoped TiO2 was prepared by sol—gel method，hydrothermal method and coprecipitation method separately，with tetrabutyl titanate，titanium isopropoxide，Ti(SO4)2 and titanium tetrachloride as titannium sources．The effects of preparation method，titanium source and calcinating temperature on the adsorbilities of the prepared Fe—V codoped TiO2 adsorbents were investigated．The adsorbents were characterized by means of XRD，SEM ，EDX，TG—DTA and FTIR．The results showed that the Fe—V mixture could remarkably improve the adsorption activity of TiO2． The adsorptive activity of Fe—V codoped TiO2 prepared by coprecipitation method was the highest in the decolourization of methylene blue solution． Under the optimal preparation con