含磺酸根和羧酸根的高固含率聚氨酯分散体稳定性的研究.pdfVIP

学兔兔 石 油 化 工 · 194· PETR0CHEMICAL TECHNOL0GY 2012年第41卷 含磺酸根和羧酸根的高固含率聚氨酯 分散体稳定性的研究 卫晓利，张发兴 (四川理工学院 材料与化学工程学院，四川 自贡 643000) [摘要]以聚醚多元醇为软段、甲苯二异氰酸酯为硬段、1，2-二羟基一3一丙磺酸钠 (DHPS)和2，2-二羟甲基丙酸(DMPA) 为复合亲水扩链剂，合成了聚氨酯 (PU)分散体；采用FTIR方法对PU分散体的结构进行了表征；考察了PU分散体的 pH稳定性、耐电解质性能、耐高温性、抗冻融性及储存稳定性。实验结果表明，PU分散体的耐电解质性能随反应体系中 m(DHPS)：m(DMPA)的增大而下降；当反应体系中0．4≤m(DHPS)：m(DMPA)≤0．6时，合成的PU分散体的固含率大于 70％(w)，Pu分散体在pH=5～10的条件下能稳定存在，8O℃时稳定性好，室温下放置6个月以上无明显的分层，经4次冻结一 融化后产生凝胶。PU分散体具有较好的pH稳定性、耐高温性、抗冻融l生及储存稳定性。 [关键词]聚醚多元醇；甲苯二异氰酸酯；聚氨酯分散体 [文章编号]1000—8144(2012)02—0194—05 [中图分类号]TQ 323．8 [文献标识码]A Stability of Polyurethane Dispersoid with High Solid Content Containing Sulfonic Group and Carboxylic Group WeiXiaoli，ZhangFaxing (DepartmentofMaterial andChemicalEngineering，SichuanInstituteofTechnology，ZigongSichuan 643000，China) [Abstract]Polyurethane(PU)dispersoids containing sulfonic groups and carboxylic groups with high solid content were synthesized from poly(tetrahydrofuran--CO--propylene oxide)glycol and toluene isocyanate with 1．2一dihydroxy一3-propanesulfonic sodium(DHPS)and dimethylol propionic acid (DMPA)as the composite hydrophilic chain—extender．The PU dispersoids were characterized by means of FTIR．Electrolyte resistance，pH stability，thermal resistance，free—thaw stability and storage stability of the PU dispersoids were investigated．The results showed that the electrolyte resistance of the PU dispersoids decreased with the increase of