临界胶束浓度的测定方法综述(国外英文资料).docVIP

临界胶束浓度的测定方法综述(国外英文资料) The method of determination of critical micelle concentration is reviewed (medical chemistry college, 11 cosmetics innovation class, yu xuefei, no. 2) Abstract: this paper introduces several methods to determine the concentration of critical micelles. Keywords: critical micellar concentration, surface tension, conductance, dyestuff, turbidity, single point ultrafiltration, fluorescence probe method Surface tension 1.1 measuring principle In the surface tension of the aqueous surfactant solution concentration is very low when fell sharply, with the increase of the concentration reaches a certain concentration (CMC) are slow change or no change. The CMC is usually determined with surface tension - a log of the concentration. Particular way is: the determination of a series of different concentration solution of surface tension gamma, make the gamma curve of LGC, extension of turning point curve on both sides of the straight line part, the concentration of the intersection point is the critical micelle concentration of the surfactant in this system. The gamma-lgc curve is the most basic data of surfactant, and can be used to find the critical micelle concentration and surface adsorption isotherm at the same time. Therefore, it is generally considered that the surface tensiometry method is the standard method for measuring the critical micellar concentration of surfactant solution. However, when a small amount of high surface activity impurities exist in the solution, such as high carbon alcohol, amine, acid substances, such as surface tension will appear low - concentration logarithm curve, not easy to determine the critical micelle concentration. Moreover, the results tend to be in error. However, from another point of view, the occurrence of the lowest surface tension curve indicates that the system contains high surface active impurities. Therefore, the surface tension - the low point of a logarithmic curve is often used as experimental eviden