测定化学需氧量(COD)的影响成分及消除方法(国外英文资料).docVIP

测定化学需氧量(COD)的影响因素及消除方法(国外英文资料) The influence factors and elimination methods of COD (COD) are measured 1. The water reducing agents of interference and the interference method to eliminate the water reducing agents and the methods of eliminating the water reducing agents usually have CL - and NO2 -, Fe2 +, S2 -, NH3 and NH4 +, etc., the existence of these ions can affect the accuracy of COD determination results. Because many experiments have shown that potassium dichromate makes water reducing the oxidation rate of the water to be 90% to 100% in acid. Therefore, it must be eliminated. The interference and elimination of 1.1 Cl The interference of 1.1.1 cl-is one of the main interference factors and has been studied by the analysis community. The concentration of the catalyst decreases with the concentration of the catalyst, and the organic matter is not completely oxidized. Under acid condition and Cl can be K2Cr207 oxidation, 6 c1 + 14 h = 3 cl2 Cr2O7 + + 2 cr + 7 h20, oxidized product of C12 can escape, and other water reducing ion oxide, such as Fe, S etc., make C0D results on the high side. 1.1.2 Cl elimination The 1.1.2.1 HgSO4 masking method is added to the 10-fold Cl - quantity HgSO4. Because Cl and HgSO4 are both difficult to dissociated and soluble, they can eliminate the interference of Cl. You can also add 20 times Cl to the HgSO4, which is better. But add mercury salt easy cause secondary pollution, liu use MnSO4 replace Ag2SO4 as catalysts, deducted by stoichiometry Cl quite COD value, the determination of COD in water, the result is satisfactory, and solve the secondary pollution of mercury salt. 1.1.2.2.the method of settling the solution of the silver nitrate solution is one: measure the amount of chlorine in the water sample in advance, and then add a certain amount of the silver nitrate to remove the Cl - interference, because the Ag + Cl = AgCl. This method is theoretically possible, but the chlorine effect is not very satisfactory. Method 2: fi