城市污泥与玉米秸秆共热解制备吸附剂的研究.PDF

40 5 Vol.40 No. 5 2011 9 Journal of China University of Mining Technology ep. 2011 张双全, 武 娜, 董明建, 吕国平, 潘亭亭 ( , 221116) : 以资源化为目的, 将城市污泥与玉米秸秆共热解, 研究了热解条件和配比对固体 物吸附 性能的影响. 以徐州污水处理厂脱水污泥为原料, 通过加入不同含量( 0~ 70%) 的玉米秸秆, 在不 同的温度下共热解制备出了含碳吸附剂. 结果表明: 在400~ 600 范围内, 吸附剂碘值随热解温 度升高而下降, 700 时的碘值又明显升高; 吸附剂的碘值随秸秆比例的增大而提高, 而比表面 2 积随热解温度和秸秆量提高而增大, 最高达150 m / g . 吸附剂的孔径分布较宽, 以中孔为主, 微 孔所占比例较小. 总孔容随热解温度的升高而增大, 随秸秆量增大而下降, 但微孔比例上升. 共热 解法制备的吸附剂的碘值和比表面积与化学法制备的污泥吸附剂相当. : 城市污泥; 玉米秸秆; 共热解; 吸附剂; 比表面积 : X 706 : A : 1000- 1964( 2011) 05-0799-05 Research on preparation of adsorbents by co-pyrolysis of sew age sludge w ith corn straw ZHAN G huang-quan, WU Na, DONG M ing-jian, LV Guo-ping, PAN Ting-ting ( chool of Chemical Engineering and T echnology, China University of Mining Technology , Xuzhou, Jiangsu 221116, China) Abstract: T he sewage sludge and corn straw w ere co-pyrolysized for utilization of sewage sludge. T he effects of co-pyrolysis conditions and the ratio of sew age sludge to corn straw on adsorption capacity of the residue w ere reseached. Taking the dew atered sew age sludge from Xuzhou Waste Water T reatment Plant as the raw material, carbon adsorbents w ere prepared by co-pyrolysis w ith corn straw in different ratios of 0- 70% at different temperatures. T he re- sults show that the iodine number of the carbon adsorbents decreased w ith the increasing of py- rolysis temperature w ithin 400 ~ 600 and increased obviously at 700 . Also the iodine number increased w ith the increasing of corn straw content. T he specific surface area of the ad- sorbents increased w ith the increasing of pyrolysis