次氯酸钠氧化改性杉木树皮螯合吸附重金属的研究-南京林业大学.doc

杉木树皮吸附重金属离子性能和动力学研究 苏文鹏，杨益琴*，蒋玲玉，周浩（南京林业大学 江苏省制浆造纸科学与技术重点实验室，江苏南京 210037摘要：Cu(II)、Cd(II)和Pb(II)重金属离子的吸附性能，详细研究了树皮粉颗粒大小、重金属离子水溶液的pH值、吸附时间和溶液的初始浓度对杉木树皮吸附重金属离子吸附量的影响，并对吸附过程的等温吸附方程和吸附动力学模型进行了模拟拟合。结果表明：杉木树皮粉可以有效地吸附水溶液中的重金属离子，树皮颗粒大小以830~250μm为宜，吸附时适宜的水溶液pH值为5，吸附时间为30min，此时对Cu(II)、Cd(II)和Pb(II)的吸附量分别为6.83mg/g、13.56mg/g和23.17mg/g。 关键词：杉木树皮；吸附；重金属离子；吸附动力学；等温吸附模型 Adsorption performance and Kinectic of Heavy Metal Ions on Fir bark from aqueous Solution SU Wen-peng1, YANG Yi-qin1 *, JIANG Ling-yu1 , ZHOU Hao1, ZHOU Yong-hong2 (1.Jiangsu Provincial Key Lab of Pulp and Paper Science and Technology, Nanjing Forestry University, Nanjing 210037, China; 2. Institute of Chemical Industry of Forestry Products, CAF, Nanjing 210042, China ) Abstract: The adsorption of copper, lead and cadmium ions (heavy metal ions, HMI) from aqueous solution on powder of fir bark was investigated by using batch techniques.The effect of pH value, contact time and initial metal ions concentration and particle size of fir bark powder on the adsorption capacity of metal ions has been studied. Fir bark was found to be a low cost and promising adsorbent of heavy metal ions from aqueous solution. The optimum adsorption conditions were as follows: contact time was 30min, the pH value of metal ions solution was 5 for Cu(II), Cd(II) and Pb(II), and the maximum adsorption capacity was reached 6.83mg/g, 13.56mg/g and 23.17mg/g respectively. Kinetics fit pseudo second-order models, hence adsorption kinetic parameters were calculated，and the correlation coefficient R2 0.997. The adsorption data of metal ions at 45oC has been described by the Freundlich and Langmuir isotherm models. Ion exchange is probably one of the major adsorption mechanisms for binding divalent metal ions to the bark powder. From these results, it can be concluded that the powder of the fir bark could be a good adsorbent for the metal ions from aqueous solution. Keywords: fir bark, adsorption, heavy metal ions, adsorption kinetic, isothermal ad