M型锶铁氧体纳米纤维静电纺丝和磁性能_刘明权.pdfVIP

25 1 Vo.l25, No.1 20 10 1 　 JournalofInorganicMaterials 　 Jan., 2010 : 1000-324X(2010)0 1-00 68-05 DOI:10.37 24 /SP.J.1077.20 10.000 68 M 刘明权, 沈湘黔, 孟献丰, 宋福展, 向 军 (江苏大学 材料科学与工程学院, 镇江 2120 13 ) :(Polyvinylpylrrolidon,e PVP), SrFeO /PVP 12 19 , M. FTIR、 TG/DSC、 XRD、 SEM VSM M., , 800℃ 2 h, M, 100 ～ 150 nm, 4 9nm, , 1000℃ 2 h 2 , 100 nm, 61 nm, 68.5A·m /kg, 50 3kA/m. 　　:M :TQ174　　　　　　:A FabricationandM agneticPropertyofM-typeStrontium FerriteNanofibersbyElectrospinning LIUMing-Quan, SHENXiang-Qian, MENGXian-Feng, SONGFu-Zhan, XIANG Jun (SchoolofMaterialsScienceandEngineering, JiangsuUniversit,y Zhenjiang2 120 13, China) Abstrac:tSrFeO /PVP compositefiberprecursorswerepreparedbyelectrospinningwithferricnitrat,e 12 19 strontium nitrateandpolyvinylpyrrolidone(PVP)asstartingreagent.sM-typestrontium ferritenanofibersare obtainedsubsequentlyfrom calcinationoftheseprecursorsat800 -1100℃.ThecompositefibersandM-type strontium ferritenanofibersarecharacterizedbyFTIR, TG/DSC, XRD, SEM andVSM.Thediametersfor thecompositefibersareinfluencedbythemetalsaltconcentrationinsolutionduringtheelectrospinning processandincreasefrom about300 nm to550 nm correspondingthemetalsaltconcentrationintherangefrom 12.5w%t to23.1w%t.TheM-typestrontium ferritenanofiberscalcinedat800℃ for2 har